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Cu and Pd Supported on Carbon for Hydrogen Production from Formic Acid: Effect of Doping the Support with Nitrogen Conference Abstracts

Conference EuropaCat-XIII: 13th European Congress on Catalysis
27-31 Aug 2017 , Florence
Source 13th European Congress on Catalysis
Compilation, 2017.
Output data Year: 2017, Article number : P3.179, Pages count : 2
Authors Bulushev D.A. 1,2 , Sobolev V.I. 1,2 , Chuvilin A.L. 3,4 , Stolyarova S.G. 2 , Asanov I.P. 2 , Zacharska M. 5 , Okotrub A.V. 2 , Bulusheva L.G. 2
Affiliations
1 Boreskov Institute of Catalysis SB RAS, Novosibirsk, 630090, Russia
2 Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk, 630090, Russia
3 CIC nanoGUNE Consolider, San Sebastian, 20018, Spain
4 IKERBASQUE, Basque Foundation for Science, Bilbao, 20013, Spain
5 University of Limerick, Limerick, Ireland

Funding (1)

1 Russian Science Foundation 16-13-00016

Abstract: Doping of carbon support with nitrogen led to an increase of the rate of hydrogen production from formic acid over 1 wt% Cu or Pd catalysts by 3-4 times. This was provided by the appearance of new active metal sites. The nature of these species was elucidated by atomic resolution HAADF/STEM, XPS, NEXAFS and CO chemisorption methods. A part of these sites represents electron-deficient single metal atoms strongly interacting with nitrogen species of the support like in complexes with 1,10-phenanthroline ligand. DFT calculations demonstrated the reactivity of such Pd single atom with respect to the formic acid molecule.
Cite: Bulushev D.A. , Sobolev V.I. , Chuvilin A.L. , Stolyarova S.G. , Asanov I.P. , Zacharska M. , Okotrub A.V. , Bulusheva L.G.
Cu and Pd Supported on Carbon for Hydrogen Production from Formic Acid: Effect of Doping the Support with Nitrogen
In compilation 13th European Congress on Catalysis. 2017. – C.344-345.
Identifiers: No identifiers
Citing: Пока нет цитирований