Effect of the Modification of Nanocrystalline MgO Aerogels with Vanadium and Carbon on the Destructive Sorption of CF2Cl2 and CFCl3 Научная публикация
| Конференция |
Bridging the Gap between Model and Real Catalysis. Energy-Related Catalysis : Third Russian-German Seminar on Catalysis 24-27 июн. 2013 , Burduguz village, Lake Baikal |
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| Журнал |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Вых. Данные | Год: 2014, Том: 55, Номер: 4, Страницы: 520-527 Страниц : 8 DOI: 10.1134/S0023158414040016 | ||||||
| Ключевые слова | Vanadium; Induction Period; Carbon Coating; Vanadium Oxide; Topochemical Reaction | ||||||
| Авторы |
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| Организации |
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Информация о финансировании (3)
| 1 | Федеральное агентство научных организаций России | V.45.3.2. |
| 2 | Российский фонд фундаментальных исследований | 12-03-00905 |
| 3 | Российский фонд фундаментальных исследований | 13-03-12227 |
Реферат:
The effect of the promotion of nanocrystalline MgO aerogels with small amounts of vanadium and carbon on the destructive sorption of the Freons CF2Cl2 and CFCl3 was studied. It was found that the introduction of the promoters considerably shortened the induction period of the reaction. The pretreatment of samples modified with vanadium in an oxidizing or reducing atmosphere did not significantly affect the duration of the induction period. It was established that the acceleration of the reaction by fine-particle carbon did not depend on the mutual arrangement of carbon and MgO: on the surface of MgO nanoparticles, in the form of their mechanical mixture, or at separate positions in a reactor. It was concluded that the modifiers catalytically affect the interaction of MgO aerogels with Freons to accelerate the formation of active centers on the surface of their nanoparticles.
Библиографическая ссылка:
Bedilo A.F.
, Volodin A.M.
, Mishakov I.V.
, Chesnokov V.V.
, Ilʹina E.V.
, Tokareva I.V.
, Shuvarakova E.I.
Effect of the Modification of Nanocrystalline MgO Aerogels with Vanadium and Carbon on the Destructive Sorption of CF2Cl2 and CFCl3
Kinetics and Catalysis. 2014. V.55. N4. P.520-527. DOI: 10.1134/S0023158414040016 WOS Scopus РИНЦ CAPlusCA OpenAlex
Effect of the Modification of Nanocrystalline MgO Aerogels with Vanadium and Carbon on the Destructive Sorption of CF2Cl2 and CFCl3
Kinetics and Catalysis. 2014. V.55. N4. P.520-527. DOI: 10.1134/S0023158414040016 WOS Scopus РИНЦ CAPlusCA OpenAlex
Оригинальная:
Бедило А.Ф.
, Володин А.М.
, Мишаков И.В.
, Чесноков В.В.
, Ильина Е.В.
, Токарева И.В.
, Шуваракова Е.И.
Влияние модифицирования нанокристаллических аэрогелей MgO ванадием и углеродом на деструктивную сорбцию CF2Cl2 И CFCl3
Кинетика и катализ. 2014. Т.55. №4. С.547-554. DOI: 10.7868/S0453881114040017 РИНЦ OpenAlex
Влияние модифицирования нанокристаллических аэрогелей MgO ванадием и углеродом на деструктивную сорбцию CF2Cl2 И CFCl3
Кинетика и катализ. 2014. Т.55. №4. С.547-554. DOI: 10.7868/S0453881114040017 РИНЦ OpenAlex
Даты:
| Поступила в редакцию: | 11 нояб. 2013 г. |
| Опубликована в печати: | 1 июл. 2014 г. |
| Опубликована online: | 5 авг. 2014 г. |
Идентификаторы БД:
| Web of science: | WOS:000340360600017 |
| Scopus: | 2-s2.0-84940268910 |
| РИНЦ: | 24954708 |
| Chemical Abstracts: | 2014:1271213 |
| Chemical Abstracts (print): | 166:191961 |
| OpenAlex: | W2030033030 |