Features of Extended XPS Spectra of C2FBr0.15 Intercalate and Silver Foil Full article
| Journal |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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| Output data | Year: 2020, Volume: 61, Number: 4, Pages: 523–532 Pages count : 10 DOI: 10.1134/S0022476620040046 | ||||||
| Tags | XPS, energy losses, valence band, conjugate electron transitions | ||||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0001 |
| 2 | Russian Foundation for Basic Research | 17-03-00049 |
Abstract:
The possibility to obtain novel data by standard electron spectroscopy and quantum chemical techniques is exemplified by C2FBr0.15 intercalate and silver foil. The features of extended X-ray photoelectron spectra are interpreted by electronic transitions in the valence band of similar unit cells. The analysis of experimental and calculated spectra reveals two states of intercalated Br2: molecular and chain-like. The interaction of Ag with NO2 at 300–520 K is limited by the formation of an oxidized state in the near-surface layer with a thickness of ∼6 A, with the metallic state of silver dominating in the Ag3d И Ag MNN spectra. Geometric parameters, states of atoms, and the character of bonds between them are consistent with the previously obtained results.
Cite:
Cholach A.R.
, Asanov I.P.
, Bryliakova A.A.
, Kalinkin A.V.
, Smirnov M.Y.
Features of Extended XPS Spectra of C2FBr0.15 Intercalate and Silver Foil
Journal of Structural Chemistry. 2020. V.61. N4. P.523–532. DOI: 10.1134/S0022476620040046 WOS Scopus РИНЦ AN OpenAlex
Features of Extended XPS Spectra of C2FBr0.15 Intercalate and Silver Foil
Journal of Structural Chemistry. 2020. V.61. N4. P.523–532. DOI: 10.1134/S0022476620040046 WOS Scopus РИНЦ AN OpenAlex
Original:
Чолач А.Р.
, Асанов И.П.
, Брылякова А.А.
, Калинкин А.В.
, Смирнов М.Ю.
Особенности протяженных РФЭ спектров интеркалата C2FBr0.15 и серебряной фольги
Журнал структурной химии. 2020. Т.61. №4. С.553-562. DOI: 10.26902/jsc_id54000 РИНЦ OpenAlex
Особенности протяженных РФЭ спектров интеркалата C2FBr0.15 и серебряной фольги
Журнал структурной химии. 2020. Т.61. №4. С.553-562. DOI: 10.26902/jsc_id54000 РИНЦ OpenAlex
Dates:
| Submitted: | Aug 13, 2019 |
| Accepted: | Nov 11, 2019 |
| Published print: | Apr 1, 2020 |
| Published online: | Jul 29, 2020 |
Identifiers:
| Web of science: | WOS:000554783300004 |
| Scopus: | 2-s2.0-85088653980 |
| Elibrary: | 45444971 |
| Chemical Abstracts: | 2020:1483711 |
| OpenAlex: | W3045838920 |