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Solid-State NMR Monitoring of a Double Bond Isomerization in Propene on ZnO Full article

Journal Chemical Physics Letters
ISSN: 0009-2614 , E-ISSN: 1873-4448
Output data Year: 2014, Volume: 607, Pages: 21-24 Pages count : 4 DOI: 10.1016/j.cplett.2014.05.048
Tags II-VI semiconductors; Light polarization; Nuclear magnetic resonance spectroscopy; Zinc oxide
Authors Gabrienko Anton A. 1 , Stepanov Alexander G. 1,2
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Prospekt Akademika Lavrentieva 5, Novosibirsk 630090, Russia
2 Novosibirsk State University, Faculty of Natural Sciences, Department of Physical Chemistry, Pirogova Street 2, Novosibirsk 630090, Russia

Funding (1)

1 Russian Foundation for Basic Research 14-03-00040

Abstract: Monitoring of the 13C-label scrambling from the position 3 to the position 1 in the 13C-labeled propene adsorbed on zinc oxide has been performed with 1H and 13C solid state NMR in situ. This allowed us to characterize the dynamics of a double bond shift reaction in adsorbed propene, and derive the kinetic parameters of this reaction, which were not earlier available without using solid state NMR and 13C-labeling of the olefin.
Cite: Gabrienko A.A. , Stepanov A.G.
Solid-State NMR Monitoring of a Double Bond Isomerization in Propene on ZnO
Chemical Physics Letters. 2014. V.607. P.21-24. DOI: 10.1016/j.cplett.2014.05.048 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Apr 17, 2014
Accepted: May 19, 2014
Published online: May 24, 2014
Published print: Jun 27, 2014
Identifiers:
Web of science: WOS:000338417400005
Scopus: 2-s2.0-84901924806
Elibrary: 24051656
Chemical Abstracts: 2014:1049614
Chemical Abstracts (print): 161:125387
OpenAlex: W1998446307
Citing:
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Web of science 5
Scopus 5
OpenAlex 4
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