Structural Study of Bimetallic Catalytic Nanosystems Containing Precious Metals by XAFS Spectroscopy | Sciact - CRIS-system of Boreskov Institute of Catalysis

Structural Study of Bimetallic Catalytic Nanosystems Containing Precious Metals by XAFS Spectroscopy Conference Abstracts

Conference

International Conference "Synchrotron and Free electron laser Radiation: generation and application"
13-17 Jul 2020 , Novosibirsk

Source

Synchrotron and Free electron laser Radiation: generation and application (SFR-2020), July 13 – 16, 2020 : Book of Abstracts
Compilation, ИЯФ СО РАН. Новосибирск.2020. 90 c. ISBN 9785904968076. РИНЦ

Output data

Year: 2020, Article number : 159, Pages count : 2

Authors

Kriventsov V.V. ¹ , Volodin A.M. ¹ , Novgorodov B.N. ¹ , Zyuzin D.A. ¹ , Aksenov D.G. ¹ , Ivanov D.P. ¹ , Iost K.N. ² , Shlyapin D.A. ² , Nikolaev S.A. ³ , Chistyakov A.V. ⁴ , Tsodikov M.V. ⁴

Affiliations

1	Boreskov Institute of Catalysis SB RAS, Lavrentiev Ave. 5, Novosibirsk, 630090, Russia
2	Center of New Chemical Technologies BIC, Neftezavodskaya St., 54, Omsk, 644040, Russia
3	Faculty of Chemistry, Moscow State University, GSP-1, 1-3 Leninskiye Gory, Moscow 1, 119991, Russia
4	Topchiev Institute of Petrochemical Synthesis RAS, Leninsky Pr., 29, Moscow, 119991, GSP-1, Russia

Funding (3)

1	Russian Foundation for Basic Research	18-03-01251
2	Russian Foundation for Basic Research	19-05-50046 (АААА-А20-120011790071-5)
3	Ministry of Science and Higher Education of the Russian Federation	05.621.21.0022 (RFMEFI62119X0022) (АААА-А20-120072290017-9)

This work presents the results of a study of the local structure of the active component of mono-, bi-metallic low-percentage (~1%) catalysts (containing Pt, Au, Pd, Ru) stabilized on oxide carriers using XAFS method (XANES/EXAFS). Studying the nature of nano-forms of noble metal stabilization is promising for creating effective catalysts for various applications, including catalytic systems for alternative energy applications. The development of synthesis methods can lead to a significant economic gain, due to the reduction of the metal content and optimization of the catalytic properties of the system. Model catalysts were prepared from mono-and bimetallic complexes, with varying synthesis methods: sol-gel, ion exchange, impregnation, reducing modes, and the nature of carriers. XAFS (XANES/EXAFS) spectra (Pt-L3, Au-L3, Pd-K, Ru-K) of studied samples were recorded at SSTRC, Novosibirsk. Genesis of the local structure of the active component was studied, including the study of oxidized precursors and catalysts after reducing and activation. It is established that depending on the background, it is possible to form various nanoscale forms of noble metals localized on the surface of the oxide carrier. Additionally, the samples were studied by XRD, XPS, XRFA, HRTEM. Variants of possible structural models are considered in detail.

Kriventsov V.V. , Volodin A.M. , Novgorodov B.N. , Zyuzin D.A. , Aksenov D.G. , Ivanov D.P. , Iost K.N. , Shlyapin D.A. , Nikolaev S.A. , Chistyakov A.V. , Tsodikov M.V.
Structural Study of Bimetallic Catalytic Nanosystems Containing Precious Metals by XAFS Spectroscopy
In compilation Synchrotron and Free electron laser Radiation: generation and application (SFR-2020), July 13 – 16, 2020 : Book of Abstracts. – ИЯФ СО РАН., 2020. – C.85-86. – ISBN 9785904968076. РИНЦ

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