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Bis-L-Cysteinium Sulfate and L-Cysteinium Methanesulfonate Full article

Journal Structural Chemistry
ISSN: 1040-0400 , E-ISSN: 1572-9001
Output data Year: 2020, Volume: 31, Pages: 1919–1925 Pages count : 7 DOI: 10.1007/s11224-020-01610-z
Tags Crystal structure; l-Cysteine; Methanesulfonate; Sulfate; Vibrational spectra
Authors Ghazaryan V.V. 1 , Drebushchak T.N. 2,3 , Boldyreva E.V. 3,4 , Petrosyan A.M. 1
Affiliations
1 Institute of Applied Problems of Physics, NAS of Armenia, 25 Nersessyan Str., Yerevan, 0014, Armenia
2 Institute of Solid State Chemistry and Mechanochemistry, SB RAS, 18 Kutateladze str., Novosibirsk, 630128, Russian Federation
3 Novosibirsk State University, 2 Pirogov Str., Novosibirsk, 630090, Russian Federation
4 Boreskov Institute of Catalysis, SB RAS, 5 Lavrentieva Ave, Novosibirsk, 630090, Russian Federation

Funding (3)

1 Russian Foundation for Basic Research 15-53-05023 (115042410027)
2 Armenian National Science & Education Fund matsc-3822
3 State Committee of Science 15RF-007

Abstract: Two new crystalline compounds of l-cysteine have been obtained: bis-l-cysteinium sulfate (l-CysH)2SO4 (I) and l-cysteinium methanesulfonate (l-CysH)CH3SO3 (II). Both crystal structures belong to the orthorhombic space group P212121. They consist of one formula unit in the asymmetric unit. Structures are stabilized due to hydrogen bonds, which are mainly of type O–H···O and N–H···O. The shortest are hydrogen bonds O–H···O between l-cysteinium cations and sulfate anion with the O···O distances of 2.567(4) Å and 2.534(4) Å in (I) and l-cysteinium cation and methanesulfonate anion with the O···O distance of 2.577(3) Å in (II). Infrared spectra were registered and discussed. © 2020, Springer Science+Business Media, LLC, part of Springer Nature.
Cite: Ghazaryan V.V. , Drebushchak T.N. , Boldyreva E.V. , Petrosyan A.M.
Bis-L-Cysteinium Sulfate and L-Cysteinium Methanesulfonate
Structural Chemistry. 2020. V.31. P.1919–1925. DOI: 10.1007/s11224-020-01610-z WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Jul 13, 2020
Accepted: Aug 7, 2020
Published online: Aug 13, 2020
Published print: Oct 1, 2020
Identifiers:
Web of science: WOS:000559270900001
Scopus: 2-s2.0-85089390368
Elibrary: 45360434
Chemical Abstracts: 2020:1591708
Chemical Abstracts (print): 173:569965
OpenAlex: W3048617121
Citing:
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Scopus 4
Web of science 4
Elibrary 3
OpenAlex 4
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