Gas-Phase Oxidation of a Propane–Propylene Mixture by Nitrous Oxide Научная публикация
| Журнал |
Industrial and Engineering Chemistry Research
ISSN: 0888-5885 , E-ISSN: 1520-5045 |
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| Вых. Данные | Год: 2020, Том: 59, Номер: 31, Страницы: 14157-14162 Страниц : 6 DOI: 10.1021/acs.iecr.0c02271 | ||
| Ключевые слова | SELECTIVE OXIDATION; KETONIZATION; METHYLENE; MECHANISM; CYCLOHEXANONE; CARBOXIDATION | ||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Федеральное агентство научных организаций России | 0303-2016-0006 (V.44.1.6) |
Реферат:
The present study focuses on a new method for obtaining C2–C3 carbonyl compounds (ketones and aldehydes) by the gas-phase selective oxidation of a propane–propylene mixture using nitrous oxide (N2O). The oxidation is carried out without catalyst in the temperature range of 623–773 K at elevated pressure. The obtained results reveal that only propylene in the propane–propylene mixture reacts with nitrous oxide. The reaction proceeds by the nonradical mechanism involving the 1,3-dipolar cycloaddition of N2O to the C═C double bond of olefin. The main reaction products are acetone, propanal, and acetaldehyde. At 723 K and a pressure of 0.7 MPa, the total selectivity to these products amounts to 74.6%, the N2O conversion attains 74.5%, and the propylene conversion is 12.5%. An important feature of the reaction is the additional formation of methylcyclopropane with a selectivity of ca. 6%.
Библиографическая ссылка:
Dubkov K.A.
, Parfenov M.V.
, Kharitonov A.S.
Gas-Phase Oxidation of a Propane–Propylene Mixture by Nitrous Oxide
Industrial and Engineering Chemistry Research. 2020. V.59. N31. P.14157-14162. DOI: 10.1021/acs.iecr.0c02271 WOS Scopus РИНЦ CAPlus OpenAlex
Gas-Phase Oxidation of a Propane–Propylene Mixture by Nitrous Oxide
Industrial and Engineering Chemistry Research. 2020. V.59. N31. P.14157-14162. DOI: 10.1021/acs.iecr.0c02271 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
| Поступила в редакцию: | 8 мая 2020 г. |
| Принята к публикации: | 10 июл. 2020 г. |
| Опубликована online: | 10 июл. 2020 г. |
| Опубликована в печати: | 5 авг. 2020 г. |
Идентификаторы БД:
| Web of science: | WOS:000558791400031 |
| Scopus: | 2-s2.0-85091141299 |
| РИНЦ: | 45275413 |
| Chemical Abstracts: | 2020:1367150 |
| OpenAlex: | W3041926573 |