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Selective Dehydrogenation of Propane to Propene with O2-H2 on Bifunctional Pt-H3PMo12O40 Catalysts Научная публикация

Журнал Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875
Вых. Данные Год: 2014, Том: 477, Страницы: 1-7 Страниц : 7 DOI: 10.1016/j.apcata.2014.03.001
Ключевые слова Dehydrogenation, Hydrogen, Oxygen, Platinum, Propane, Propene
Авторы Kuznetsova N.I. 1 , Popova G.Ya. 1 , Kuznetsova L.I. 1 , Zaikovskii V.I. 1,2 , Koscheev S.V. 1 , Chesalov Yu.A. 1 , Andrushkevich T.V. 1 , Lisitsyn A.S. 1 , Likholobov V.A. 3 , Han S. 4
Организации
1 Boreskov Institute of Catalysis, Novosibirsk 630090, Russian Federation
2 Novosibirsk State University, Novosibirsk 630090, Russian Federation
3 Institute of Hydrocarbons Processing, Omsk 644040, Russian Federation
4 Rohm and Haas Company, Spring House, PA 19477-0904, USA

Реферат: Properties of Pt/SiO2 catalysts modified by a heteropoly acid (HPA) were studied in oxidative dehydrogenation of propane with an O2 and H2 mixture. The catalysts were characterized with N2 adsorption, IRS, XPS, and HAADF-STEM coupled with EDX, and the possibility for Pt and HPA to be highly dispersed and well-mixed on the silica surface has been shown. In the presence of O2 and H2, propene could be obtained at temperatures as low as 150 °C, but heating to 200 °C provided much better selectivity (up to 94–96% at propane conversion of 2–4%). The process probably proceeded through oxidation of propane with peroxo species to C3-alcohols on Pt sites, followed by dehydration of the alcohols on the acid sites of HPA. The catalytic properties were strongly dependent both on the feed composition (the C3H8/H2/O2/N2 ratio) and on the composition of catalysts, optimum HPA loading being 20–30 wt.% at 0.2–1 wt.% of Pt. Under optimal operating conditions, a space time yield of propene was at a level of 420 g kgcat−1 h−1, without a tendency to decline with time on stream.
Библиографическая ссылка: Kuznetsova N.I. , Popova G.Y. , Kuznetsova L.I. , Zaikovskii V.I. , Koscheev S.V. , Chesalov Y.A. , Andrushkevich T.V. , Lisitsyn A.S. , Likholobov V.A. , Han S.
Selective Dehydrogenation of Propane to Propene with O2-H2 on Bifunctional Pt-H3PMo12O40 Catalysts
Applied Catalysis A: General. 2014. V.477. P.1-7. DOI: 10.1016/j.apcata.2014.03.001 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 26 авг. 2013 г.
Принята к публикации: 1 мар. 2014 г.
Опубликована online: 11 мар. 2014 г.
Опубликована в печати: 5 мая 2014 г.
Идентификаторы БД:
Web of science: WOS:000336468800001
Scopus: 2-s2.0-84897899494
РИНЦ: 21871498
Chemical Abstracts: 2014:676124
Chemical Abstracts (print): 160:636908
OpenAlex: W1963804209
Цитирование в БД:
БД Цитирований
Web of science 10
Scopus 10
РИНЦ 10
OpenAlex 10
Альметрики: