Sciact
  • EN
  • RU

Tungsten Peroxopolyoxo Complexes as Advanced Catalysts for the Oxidation of Organic Compounds with Hydrogen Peroxide Full article

Journal Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875
Output data Year: 2020, Volume: 604, Article number : 117786, Pages count : 10 DOI: 10.1016/j.apcata.2020.117786
Tags EXAFS; hydrogen peroxide; metal complex catalysis; organic compounds oxidation; peroxopolyoxotungstates
Authors Pai Zinaida P. 1 , Chesalov Yuriy A. 1 , Berdnikova Polina V. 1 , Uslamin Evgeny A. 1 , Yushchenko Dmitry Yu. 1 , Uchenova Yulia V. 1 , Khlebnikova Tatiana B. 1 , Baltakhinov Vladimir P. 1 , Kochubey Dmitry I. 1 , Bukhtiyarov Valerii I. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences (SB RAS), 630090 Novosibirsk, Lavrentiev Ave., 5, Russian Federation

Funding (1)

1 Federal Agency for Scientific Organizations 0303-2016-0008

Abstract: Selective oxidation of organic substrates by environment-friendly oxidizing agents is an important ingredient of the sustainable chemical industry. Here we report a comprehensive study in the field of metal peoroxocomplex catalysis for the selective liquid phase oxidation of various organic substrates. A number of well-defined bi-functional tungsten complex catalysts with tetra nuclear structure {PO4[WO(O2)2]4}3- in combination with a phase-transfer agents were synthesized. The structural properties were thoroughly studied using of IR, Raman and EXAFS spectroscopy. By combining different spectroscopy techniques were able to elucidate the effect of quaternary ammonium cations on the structural properties of the resulting peroxo complexes. The catalytic properties of these well-defined material were then evaluated in bi-phasic selective oxidation of cyclooctene, methyl oleate and N-phosphonomethyliminodiacetic acid with hydrogen peroxide under mild conditions. For every substrate we were able to achieve high conversion at the selectivity towards a target product close to 100%. © 2020 Elsevier B.V.
Cite: Pai Z.P. , Chesalov Y.A. , Berdnikova P.V. , Uslamin E.A. , Yushchenko D.Y. , Uchenova Y.V. , Khlebnikova T.B. , Baltakhinov V.P. , Kochubey D.I. , Bukhtiyarov V.I.
Tungsten Peroxopolyoxo Complexes as Advanced Catalysts for the Oxidation of Organic Compounds with Hydrogen Peroxide
Applied Catalysis A: General. 2020. V.604. 117786 :1-10. DOI: 10.1016/j.apcata.2020.117786 WOS Scopus РИНЦ AN OpenAlex
Dates:
Submitted: Apr 13, 2020
Accepted: Aug 13, 2020
Published online: Aug 18, 2020
Published print: Aug 25, 2020
Identifiers:
Web of science: WOS:000573462900002
Scopus: 2-s2.0-85089698085
Elibrary: 45350948
Chemical Abstracts: 2020:1667264
OpenAlex: W3049250060
Citing:
DB Citing
Scopus 23
Web of science 23
Elibrary 21
OpenAlex 26
Altmetrics: