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Catalytic Properties of Nanosized Cu/ZrO2 Systems in the Steam Reforming of Bioethanol Full article

Journal Theoretical and Experimental Chemistry
ISSN: 0040-5760 , E-ISSN: 1573-935X
Output data Year: 2014, Volume: 50, Number: 1, Pages: 46-52 Pages count : 7 DOI: 10.1007/s11237-014-9347-9
Tags bioethanol, catalyst, copper, dehydrogenation, steam reforming, temperature-programmed reduction, yttrium-stabilized zirconium dioxide
Authors Dejnega I.V. 1 , Dolgikh L.Yu. 1 , Staraya L.A. 1 , Strizhak P.E. 1 , Moroz E.M. 2 , Pakharukova V.P. 2
Affiliations
1 L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, Kyiv 03028, Ukraine
2 Boreskov Institute of Catalysis, Siberian Branch, Prospekt Lavrentieva, 5, Novosibirsk 630090, Russian Federation

Abstract: A size effect was found in the low-temperature steam reforming of bioethanol (15 vol. % ethanol in water) on copper catalysts supported on yttrium-stabilized zirconia: the specific rate of the conversion of ethanol into the key reforming product, acetaldehyde, is virtually independent on the mean diameter of the copper particles in the range 6-10 nm but drops significantly for particles with diameter 1-2 nm. Hypotheses for this observed effect are presented.
Cite: Dejnega I.V. , Dolgikh L.Y. , Staraya L.A. , Strizhak P.E. , Moroz E.M. , Pakharukova V.P.
Catalytic Properties of Nanosized Cu/ZrO2 Systems in the Steam Reforming of Bioethanol
Theoretical and Experimental Chemistry. 2014. V.50. N1. P.46-52. DOI: 10.1007/s11237-014-9347-9 WOS Scopus РИНЦ ANCAN OpenAlex
Original: Дейнега И.В. , Долгих Л.Ю. , Старая Л.А. , Стрижак П.Е. , Мороз Э.М. , Пахарукова В.П.
Каталитические свойства наноразмерных систем Cu/ZrO2 в процессе парового риформинга биоэтанола
Теоретическая и экспериментальная химия. 2014. Т.50. №1. С.46-52. РИНЦ
Dates:
Submitted: Dec 30, 2013
Published print: Mar 1, 2014
Published online: Apr 22, 2014
Identifiers:
Web of science: WOS:000338141700006
Scopus: 2-s2.0-84899916662
Elibrary: 21877019
Chemical Abstracts: 2014:652684
Chemical Abstracts (print): 163:94150
OpenAlex: W2432606767
Citing:
DB Citing
Web of science 4
Scopus 4
Elibrary 4
OpenAlex 3
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