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Recent Developments in Liquid-Phase Selective Oxidation Using Environmentally Benign Oxidants and Mesoporous Metal Silicates Review

Journal Catalysis Science and Technology
ISSN: 2044-4753 , E-ISSN: 2044-4761
Output data Year: 2014, Volume: 4, Number: 7, Pages: 1869-1889 Pages count : 21 DOI: 10.1039/C4CY00087K
Tags Catalysts; Liquids; Oxidants; Oxidation; Reusability; Silicates
Authors Kholdeeva Oxana A. 1,2
Affiliations
1 Boreskov Institute of Catalysis, Lavrentieva 5, Novosibirsk, Russia
2 Novosibirsk State University, Pirogova str. 2, Novosibirsk, Russia

Funding (2)

1 Russian Foundation for Basic Research 13-03-92699
2 The Ministry of Education and Science of the Russian Federation

Abstract: This Perspective article surveys recent advances in the synthesis of mesoporous transition-metal-containing silicate materials and their use for the liquid-phase selective oxidation of organic compounds (alkanes, alkenes, aromatics, S-compounds, etc.) with environmentally friendly oxidants – molecular oxygen, hydrogen peroxide and organic hydroperoxides. A selection of the most relevant results reported thus far in the literature is provided, with particular attention paid to the issues of the nature of catalysis, catalyst stability and reusability. Approaches elaborated in recent years to create hydrothermally stable mesoporous metal silicates are considered, and the scope and limitations of such catalysts in liquid-phase oxidations are discussed.
Cite: Kholdeeva O.A.
Recent Developments in Liquid-Phase Selective Oxidation Using Environmentally Benign Oxidants and Mesoporous Metal Silicates
Catalysis Science and Technology. 2014. V.4. N7. P.1869-1889. DOI: 10.1039/C4CY00087K WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Jan 21, 2014
Accepted: Feb 26, 2014
Published online: Feb 27, 2014
Identifiers:
Web of science: WOS:000337132100002
Scopus: 2-s2.0-84902179500
Elibrary: 24054562
Chemical Abstracts: 2014:946094
Chemical Abstracts (print): 161:10009
OpenAlex: W2135184348
Citing:
DB Citing
Web of science 84
Scopus 83
Elibrary 70
OpenAlex 87
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