Effect of the Ni/Cu Ratio on the Composition and Catalytic Properties of Nickel-Copper Alloy in Anisole Hhydrodeoxygenation Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2014, Volume: 55, Number: 1, Pages: 69-78 Pages count : 10 DOI: 10.1134/S0023158414010145 | ||||||
| Tags | Anisole; Nickel Content; Copper Metal; Hydrodeoxygenation; Lower Surface Free Energy | ||||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | The Ministry of Education and Science of the Russian Federation | 16.526.11.6003 |
| 2 | The Ministry of Education and Science of the Russian Federation | 16.740.11.0683 |
Abstract:
The activity of NiCu-SiO2 catalysts with a metal content of 90% and different Ni/Cu ratios has been investigated in the hydrodeoxygenation of anisole, a model compound of bio-oil, at 280°C and 6 MPa. A homogeneous phase composition of the active component has been synthesized by the co-decomposition of nickel and copper nitrates followed by the introduction of SiO2 as a stabilizer. The resulting catalysts have been characterized by temperature-programmed reduction, X-ray powder diffraction, X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy combined with energy-dispersive microanalysis. The bulk and surface composition of active-component particles has been determined by XPS and X-ray diffraction. In all of the catalysts containing 15–85 wt % Ni, there are two types of solid solutions. One has a constant composition, Cu0.95Ni0.05, which is independent of the Ni/Cu ratio in the catalyst; in the other, the nickel stoichiometry increases with an increasing Ni content of the active component. A correlation has been established between the Ni/Cu ratio and the rate constants of the reaction examined and between the Ni/Cu ratio and the degree of hydrodeoxygenation for all samples. The most active catalyst is Ni85Cu5-SiO2.
Cite:
Smirnov A.A.
, Khromova S.A.
, Bulavchenko O.A.
, Kaichev V.V.
, Saraev A.A.
, Reshetnikov S.I.
, Bykova M.V.
, Trusov L.I.
, Yakovlev V.A.
Effect of the Ni/Cu Ratio on the Composition and Catalytic Properties of Nickel-Copper Alloy in Anisole Hhydrodeoxygenation
Kinetics and Catalysis. 2014. V.55. N1. P.69-78. DOI: 10.1134/S0023158414010145 WOS Scopus РИНЦ ANCAN OpenAlex
Effect of the Ni/Cu Ratio on the Composition and Catalytic Properties of Nickel-Copper Alloy in Anisole Hhydrodeoxygenation
Kinetics and Catalysis. 2014. V.55. N1. P.69-78. DOI: 10.1134/S0023158414010145 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Смирнов А.А.
, Хромова С.А.
, Булавченко О.А.
, Каичев В.В.
, Сараев А.А.
, Решетников С.И.
, Быкова М.В.
, Трусов Л.И.
, Яковлев В.А.
Влияние соотношения Ni/Cu на состав и каталитические свойства никельмедного сплава в реакции гидродеоксигенации анизола
Кинетика и катализ. 2014. Т.55. №1. С.72-81. DOI: 10.7868/S0453881114010158 РИНЦ OpenAlex
Влияние соотношения Ni/Cu на состав и каталитические свойства никельмедного сплава в реакции гидродеоксигенации анизола
Кинетика и катализ. 2014. Т.55. №1. С.72-81. DOI: 10.7868/S0453881114010158 РИНЦ OpenAlex
Dates:
| Submitted: | Feb 28, 2013 |
| Published print: | Jan 1, 2014 |
| Published online: | Feb 27, 2014 |
Identifiers:
| Web of science: | WOS:000332333700010 |
| Scopus: | 2-s2.0-84897820962 |
| Elibrary: | 21871255 |
| Chemical Abstracts: | 2014:329395 |
| Chemical Abstracts (print): | 160:577493 |
| OpenAlex: | W2027709524 |