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Intermediate Temperature Proton Electrolytes Based on Cesium Dihydrogen Phosphate and Butvar Polymer Научная публикация

Журнал Ionics
ISSN: 0947-7047 , E-ISSN: 1862-0760
Вых. Данные Год: 2020, Том: 26, Номер: 4, Страницы: 1813-1818 Страниц : 6 DOI: 10.1007/s11581-020-03505-9
Ключевые слова Proton conductivity . Acid salt . Cesium dihydrogen phosphate . Polyvinyl butyral . Composite polymer electrolyte
Авторы Bagryantseva Irina N. 1,2 , Gaydamaka Anna A. 2 , Ponomareva Valentina G 1,2
Организации
1 Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of the Russian Academy of Sciences
2 Novosibirsk State University

Реферат: The phase composition, electrotransport properties, and spectral characteristics of the (1 − x)CsH2PO4–xButvar system (х = 0–0.2 wt%) were investigated in details. Butvar was proved to be a chemically suitable matrix for CsH2PO4 with a good adhesion to acid salt permitting the formation of flexible membrane. The chemical interaction of organic matrix with acid salt was not observed. A new method of “polymer-CsH2PO4” composites preparation through alcohol solutions of initial components was proposed. The flexible and thin (~ 200 μm) proton membranes with uniform salt distribution were obtained. Composite polymer electrolytes are characterized by high proton conductivity values (~ 5 × 10−3 S/cm) at 240 °C and are stable under conditions of high humidity (PH2O ~ 0.3 atm.).
Библиографическая ссылка: Bagryantseva I.N. , Gaydamaka A.A. , Ponomareva V.G.
Intermediate Temperature Proton Electrolytes Based on Cesium Dihydrogen Phosphate and Butvar Polymer
Ionics. 2020. V.26. N4. P.1813-1818. DOI: 10.1007/s11581-020-03505-9 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 8 окт. 2019 г.
Принята к публикации: 20 февр. 2020 г.
Опубликована online: 7 мар. 2020 г.
Опубликована в печати: 1 апр. 2020 г.
Идентификаторы БД:
Web of science: WOS:000521777200025
Scopus: 2-s2.0-85081662437
РИНЦ: 43251379
Chemical Abstracts: 2020:463776
Chemical Abstracts (print): 173:921398
OpenAlex: W3010138592
Цитирование в БД:
БД Цитирований
Scopus 16
Web of science 15
OpenAlex 18
Альметрики: