Maleates of Mn(II), Fe(II), Co(II), and Ni(II) as Precursors for Synthesis of Metal-Polymer Composites | Sciact - CRIS-system of Boreskov Institute of Catalysis

Maleates of Mn(II), Fe(II), Co(II), and Ni(II) as Precursors for Synthesis of Metal-Polymer Composites Full article

Journal

Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 , E-ISSN: 1531-8613

Output data

Year: 2014, Volume: 59, Number: 10, Pages: 1180-1186 Pages count : 7 DOI: 10.1134/S0036023614100222

Tags

Acid Maleate; Thermolysis; Normal Maleate; Metal Carboxylate; Transition Metal Salt

Authors

Yudanova L.I. ¹ , Logvinenko V.A. ¹ , Sheludyakova L.A. ¹ , Yudanov N.F. ¹ , Semyannikov P.P. ¹ , Kozhemyachenko S.I. ¹ , Korolʹkov I.V. ¹ , Rudina N.A. ² , Ishchenko A.V. ²

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090 Russia
2	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, pr. Lavrent’eva 5, Novosibirsk, 630090 Russia

Comparison was made for the structural, IR spectral, and thermoanalytical characteristics of normal [M1(H2O)2(C4H2O4)](H2O) (M1 = Co(II) and Ni(II)) and acid maleates [M2(H2O)4(C4H3O4)2] (M2 = Mn(II), Fe(II), Co(II) and Ni(II)). Only structures of acid maleates contain intramolecular asymmetric hydrogen bond whose asymmetry increases in the series of transition metal salts. Thermal decomposition of Co(II), Ni(II) normal maleates, and Mn(II), Fe(II), Co(II), Ni(II) acid maleates proceeds in three stages. Onset decomposition temperatures for the first and second stages decreases in the series of normal maleates Co(II) ≥ Ni(II) and increases in the series of acid maleates Fe(II) < Co(II) < Ni(II) ≈ Mn(II). Onset temperature of the third stage decreases in the series of both normal maleates Co(II) > Ni(II) and acid maleates Mn(II) > Fe(II) > Co(II) > Ni(II).

Yudanova L.I. , Logvinenko V.A. , Sheludyakova L.A. , Yudanov N.F. , Semyannikov P.P. , Kozhemyachenko S.I. , Korolʹkov I.V. , Rudina N.A. , Ishchenko A.V.
Maleates of Mn(II), Fe(II), Co(II), and Ni(II) as Precursors for Synthesis of Metal-Polymer Composites
Russian Journal of Inorganic Chemistry. 2014. V.59. N10. P.1180-1186. DOI: 10.1134/S0036023614100222 WOS Scopus РИНЦ OpenAlex ANCAN

Юданова Л.И. , Логвиненко В.А. , Шелудякова Л.А. , Юданов Н.Ф. , Семянников П.П. , Кожемяченко С.И. , Корольков И.В. , Рудина Н.А. , Ищенко А.В.
Соли малеиновой кислоты Mn(II), Fe(II), Co(II), Ni(II) - прекурсоры для синтеза композитов металл-полимер
Журнал неорганической химии. 2014. Т.59. №10. С.1420-1426. DOI: 10.7868/S0044457X14100237 РИНЦ OpenAlex

Submitted:	Sep 5, 2013
Published online:	Sep 25, 2014
Published print:	Oct 1, 2014

≡ Web of science:	WOS:000342456100019
≡ Scopus:	2-s2.0-84919385284
≡ Elibrary:	24019937
≡ OpenAlex:	W2138353883
≡ Chemical Abstracts:	2014:1610093
≡ Chemical Abstracts (print):	162:384134

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≡ Scopus	11	Сбор данных от 15.02.2026
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≡ OpenAlex	13	Сбор данных от 15.02.2026