Dynamics in Nanoporous Materials Probed by 2H Solid State NMR: Estimation of Self-Diffusion Coefficients | Sciact - CRIS-system of Boreskov Institute of Catalysis

Dynamics in Nanoporous Materials Probed by 2H Solid State NMR: Estimation of Self-Diffusion Coefficients Full article

Journal

Adsorption
ISSN: 0929-5607 , E-ISSN: 1572-8757

Output data

Year: 2021, Volume: 27, Number: 5, Pages: 841-855 Pages count : 15 DOI: 10.1007/s10450-020-00256-x

Tags

2H solid-state NMR; Dynamics in confined geometries; Einstein equation for diffusivity; Hydrocarbons; Metal–organic frameworks (MOFs); Self-diffusion; Zeolites

Authors

Kolokolov Daniil I. ^1,2 , Freude Dieter ³ , Stepanov Alexander G. ^1,2

Affiliations

1	Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences, Prospekt Akademika Lavrentieva 5, Novosibirsk, Russia 630090
2	Novosibirsk State University, Pirogova Street 2, Novosibirsk, Russia 630090
3	Fakultät für Physik Und Geowissenschaften, Universität Leipzig, Linnéstr. 5, 04103 Leipzig, Germany

Funding (2)

1	Federal Agency for Scientific Organizations	0303-2016-0003
2	Russian Foundation for Basic Research	18-29-04009

2H solid-state NMR represents a reliable method for probing the dynamics of the molecules in confined geometries, including microporous and mesoporous materials such as zeolites or metal–organic frameworks (MOFs). Dynamic characteristics derived from analyses of 2H NMR line shape and spin relaxation for adsorbed deuterated molecules can be related with translational motions along the porous framework. This opens up the possibility to use 2H NMR for probing self-diffusion within porous materials. Herein we discuss the basic principles and approaches that can be used to derive the information on diffusion coefficients based on analysis of the dynamics of confined molecules by 2H NMR. We discuss the corresponding possibilities and limitations of 2H NMR compared to other experimental methods, such QENS and PFG NMR. Several examples for estimation of diffusion coefficients by 2H NMR for alkanes, olefins, alcohol, benzene, pyridine in zeolites and MOFs are provided. © 2020, Springer Science+Business Media, LLC, part of Springer Nature.

Kolokolov D.I. , Freude D. , Stepanov A.G.
Dynamics in Nanoporous Materials Probed by 2H Solid State NMR: Estimation of Self-Diffusion Coefficients
Adsorption. 2021. V.27. N5. P.841-855. DOI: 10.1007/s10450-020-00256-x WOS Scopus РИНЦ AN OpenAlex

Submitted:	Apr 13, 2020
Accepted:	Aug 12, 2020
Published online:	Sep 27, 2020
Published print:	Jul 1, 2021

Web of science:	WOS:000573188800001
Scopus:	2-s2.0-85091612168
Elibrary:	45263126
Chemical Abstracts:	2020:1930773
OpenAlex:	W3087846729

DB	Citing
Scopus	10
Web of science	11
Elibrary	8
OpenAlex	12