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Advanced Green Approaches for the Synthesis of NiCu-Containing Catalysts for the Hydrodeoxygenation of Anisole Full article

Journal Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308
Output data Year: 2020, Volume: 379, Pages: 262-271 Pages count : 10 DOI: 10.1016/j.cattod.2020.09.006
Tags Heterogeneous catalysts; Bio-oil; Hydrodeoxygenation; Green chemistry; Supercritical antisolvent
Authors Nesterov N.S. 1 , Smirnov A.A. 1 , Pakharukova V.P. 1 , Yakovlev V.A. 1 , Martyanov O.N. 1
Affiliations
1 Boreskov Institute of Catalysis, Lavrentieva Ave., 5, Novosibirsk, 630090, Russia

Funding (2)

1 Russian Foundation for Basic Research 18-29-06022
2 Ministry of Science and Higher Education of the Russian Federation 075-15-2019-1876

Abstract: NiCu-containing catalysts stabilized by SiO2 with a different metals ratio are prepared via the «green» supercritical antisolvent (SAS) precipitation method. Obtained catalysts are characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and CO adsorption. The addition of water and a silica sol into precursor solution allows us to obtain highly loaded (70 wt. % of metals) dispersed metal catalysts with a Ni1-xCux solid solution structure without phase separation into individual metals. These heterogeneous catalysts are used for hydrodeoxygenation of anisole – a model compound of pyrolysis liquid. The main product of the hydrodeoxygenation process over prepared catalysts was cyclohexane.
Cite: Nesterov N.S. , Smirnov A.A. , Pakharukova V.P. , Yakovlev V.A. , Martyanov O.N.
Advanced Green Approaches for the Synthesis of NiCu-Containing Catalysts for the Hydrodeoxygenation of Anisole
Catalysis Today. 2020. V.379. P.262-271. DOI: 10.1016/j.cattod.2020.09.006 WOS Scopus РИНЦ AN OpenAlex
Dates:
Submitted: Jan 28, 2020
Accepted: Sep 1, 2020
Published print: Sep 1, 2020
Published online: Sep 16, 2020
Identifiers:
Web of science: WOS:000687320400002
Scopus: 2-s2.0-85091686960
Elibrary: 45301234
Chemical Abstracts: 2020:1960143
OpenAlex: W3087294454
Citing:
DB Citing
Scopus 35
Elibrary 36
Web of science 31
OpenAlex 33
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