Novel Materials for Solid Oxide Fuel Cells Cathodes and Oxygen Separation Membranes: Fundamentals of Oxygen Transport and Performance | Sciact - CRIS-system of Boreskov Institute of Catalysis

Novel Materials for Solid Oxide Fuel Cells Cathodes and Oxygen Separation Membranes: Fundamentals of Oxygen Transport and Performance Full article

Journal

Carbon Resources Conversion
, E-ISSN: 2588-9133

Output data

Year: 2020, Volume: 3, Pages: 112-121 Pages count : 10 DOI: 10.1016/j.crcon.2020.08.002

Tags

Solid oxide fuel cells; Oxygen separation membranes; Oxygen mobility; Perovskites; Nanocomposites; Ruddlesden – Popper phases

Authors

Sadykov Vladislav A. ^1,2 , Sadovskaya Ekaterina M. ^1,2 , Eremeev Nikita F. ¹ , Pikalova Elena Yu. ^3,4 , Bogdanovich Nina M. ³ , Filonova Elena A. ⁴ , Krieger Tamara A. ^1,2 , Fedorova Yulia E. ¹ , Krasnov Alexey V. ^1,2 , Skriabin Pavel I. ¹ , Lukashevich Anton I. ¹ , Steinberger-Wilckens Robert ⁵ , Vinke Izaak C. ⁶

Affiliations

1	Federal Research Center Boreskov Institute of Catalysis SB RAS, 630090 Novosibirsk, Russia
2	Novosibirsk State University, 630090 Novosibirsk, Russia
3	Institute of High Temperature Electrochemistry UB RAS, 620137 Yekaterinburg, Russia
4	Ural Federal University, 620002 Yekaterinburg, Russia
5	University of Birmingham, Edgbaston, Birmingham B15 2TT, UK
6	Forschungszentrum Jülich GmbH, 52425 Jülich, Germany

Funding (3)

1	Russian Science Foundation	16-13-00112
2	Federal Agency for Scientific Organizations	0303-2016-0013
3	The Ministry of Education and Science of the Russian Federation	02.A03.21.0006

In the field of modern hydrogen energy, obtaining pure hydrogen and syngas and then being able to use them for green energy production are significant problems. Developing solid oxide fuel cells (SOFC) and catalytic membranes for oxygen separation as well as materials for these devices is one of the most likely ways to solve these problems. In this work, the authors’ recent studies in this field are reviewed; the fundamentals of developing materials for SOFC cathodes and oxygen separation membranes’ permselective layers based on research of their oxygen mobility and surface reactivity are presented. Ruddlesden – Popper phases Ln2–xCaxNiO4+δ (LnCNO) and perovskite-fluorite nanocomposites PrNi0.5Co0.5O3–δ–Ce0.9Y0.1O2–δ (PNC–YDC) were studied by isotope exchange of oxygen with C18O2 and 18O2 in flow and closed reactors. For LnCNO a high oxygen mobility was shown (D* ~ 10–7 cm2/s at 700 °C), being provided by the cooperative mechanism of oxygen migration involving both regular and highly-mobile interstitial oxygen. For PNC–YDC dominated a wide fast diffusion channel via fluorite phase and interphases due to features of the redistribution of cations resulting in superior oxygen mobility (D* ~ 10–8 cm2/s at 700 °C). After optimization of composition and nanodomain structure of these materials, as cathodes of SOFC they provided a high power density, while for asymmetric supported oxygen separation membranes – a high oxygen permeability.

Sadykov V.A. , Sadovskaya E.M. , Eremeev N.F. , Pikalova E.Y. , Bogdanovich N.M. , Filonova E.A. , Krieger T.A. , Fedorova Y.E. , Krasnov A.V. , Skriabin P.I. , Lukashevich A.I. , Steinberger-Wilckens R. , Vinke I.C.
Novel Materials for Solid Oxide Fuel Cells Cathodes and Oxygen Separation Membranes: Fundamentals of Oxygen Transport and Performance

Carbon Resources Conversion. 2020. V.3. P.112-121. DOI: 10.1016/j.crcon.2020.08.002 WOS Scopus РИНЦ AN OpenAlex

Full text from publisher

Submitted:	May 22, 2020
Accepted:	Aug 30, 2020
Published online:	Sep 11, 2020

Web of science:	WOS:000879183000001
Scopus:	2-s2.0-85101369075
Elibrary:	46750675
Chemical Abstracts:	2020:1964956
OpenAlex:	W3086409238

DB	Citing
Scopus	26
Elibrary	31
OpenAlex	27
Web of science	26