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Photoluminescence Properties of Microspherical Alumina-Chromium Catalyst Full article

Journal Inorganic Materials: Applied Research
ISSN: 2075-1133 , E-ISSN: 2075-115X
Output data Year: 2014, Volume: 5, Number: 5, Pages: 476-481 Pages count : 6 DOI: 10.1134/S2075113314050153
Tags centrifugal thermal activation product of gibbsite, Cr3+ photoluminescence, dehydrogenation of light alkanes, industrial alumina-chromium catalyst IM-2201, model alumina-chromium catalysts, α and γ phases of Al2O3
Authors Rastorguev A.A. 1 , Baronskiy M.G. 1 , Zaitseva N.A. 1 , Isupova L.A. 1 , Kostyukov A.I. 1 , Larina T.V. 1 , Pakhomov N.A. 1 , Snytnikov V.N. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Abstract: The electronic structure of the model alumina-chromium catalyst CrO x /Al2O3 for isobutane isomerization was investigated using the method of steady-state photoluminescence (PL). The chromium content varied in the investigated samples from 0.1 to 11.0 wt % in terms of Cr2O3. The luminescence and luminescence excitation spectra of Cr3+ were recorded under conditions of strong reabsorption. The feasibility of the Cr3+: Al2O3 (α-, γ-Al2O3) polymorphic phase detection and separation of the surface and bulk luminescence was shown. The Cr3+ luminescence and luminescence excitation spectra of the industrial catalyst IM-2201 were recorded.
Cite: Rastorguev A.A. , Baronskiy M.G. , Zaitseva N.A. , Isupova L.A. , Kostyukov A.I. , Larina T.V. , Pakhomov N.A. , Snytnikov V.N.
Photoluminescence Properties of Microspherical Alumina-Chromium Catalyst
Inorganic Materials: Applied Research. 2014. V.5. N5. P.476-481. DOI: 10.1134/S2075113314050153 Scopus РИНЦ OpenAlex
Original: Расторгуев А.А. , Баронский М.Г. , Зайцева Н.А. , Исупова Л.А. , Костюков А.И. , Ларина Т.В. , Пахомов Н.А. , Снытников В.Н.
Фотолюминесцентные свойства микросферического алюмохромового катализатора
Перспективные материалы. 2014. №2. С.11-17. RSCI РИНЦ ANCAN
Dates:
Submitted: Jun 5, 2013
Published print: Sep 1, 2014
Published online: Oct 24, 2014
Identifiers:
Scopus: 2-s2.0-84919597070
Elibrary: 24020795
OpenAlex: W2016666023
Citing:
DB Citing
Scopus 12
Elibrary 13
OpenAlex 12
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