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Catalytic Combustion of Sulfur-Containing Liquid Fuels in the Fluidized Bed: Experiment and Modeling Научная публикация

Журнал Journal of Industrial and Engineering Chemistry
ISSN: 1226-086X
Вых. Данные Год: 2021, Том: 93, Страницы: 163-169 Страниц : 7 DOI: 10.1016/j.jiec.2020.09.010
Ключевые слова Catalytic combustion; Fluidized bed; Sulfur-Containing liquid fuels; Sulfur oxides; Calcite; Modelling
Авторы Dubinin Yury V. 1 , Yazykov Nikolay A. 1 , Reshetnikov Sergei I. 1 , Yakovlev Vadim A. 1
Организации
1 Federal Research Center Boreskov Institute of Catalysis SB RAS

Информация о финансировании (1)

1 Российский научный фонд 17-73-30032

Реферат: Environmentally safe fuel combustion is an actual worldwide problem. The alternative technology of combustion in fluidized bed of catalyst was developed in the Boreskov Institute of Catalysis. The technology allows one to conduct the process at 400–700 оC and significantly reduce outlet concentrations of toxic compounds. However, the use of sulfur oils as fuel demands solving a problem of the decreasing the outlet SO2 concentration because the oils contain small amount of ash to absorb SO2. The work is devoted to study features of sulfur light oil and high-sulfur heavy oil combustion in the fluidized bed of the Al–Cu–Cr-oxide catalyst. Reduction of SO2 emission at conserving oxidation degree of oils within range of 99.5–99.8% might be reached by using a non-isothermal temperature profile in the reactor as well as a use of CaCO3 or CaO at Ca/S > 2 to absorb sulfur oxides. The non-isothermal temperature profile in the reactor consisted of an oxidation zone with the temperature in the fluidized bed of 700 оC and a catalytic oxidation of SO2 to SO3 zone with equilibrium shift to reducing SO2 concentration because of the temperature change from 700 оC to 585 оC.
Библиографическая ссылка: Dubinin Y.V. , Yazykov N.A. , Reshetnikov S.I. , Yakovlev V.A.
Catalytic Combustion of Sulfur-Containing Liquid Fuels in the Fluidized Bed: Experiment and Modeling
Journal of Industrial and Engineering Chemistry. 2021. V.93. P.163-169. DOI: 10.1016/j.jiec.2020.09.010 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 13 нояб. 2019 г.
Принята к публикации: 14 сент. 2020 г.
Опубликована online: 24 сент. 2020 г.
Опубликована в печати: 25 янв. 2021 г.
Идентификаторы БД:
Web of science: WOS:000594534900008
Scopus: 2-s2.0-85093927635
РИНЦ: 45202163
Chemical Abstracts: 2020:2171989
Chemical Abstracts (print): 174:260505
OpenAlex: W3088540903
Цитирование в БД:
БД Цитирований
Scopus 8
Web of science 8
РИНЦ 9
OpenAlex 8
Альметрики: