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Non-Heme Manganese Complexes Catalyzed Asymmetric Epoxidation of Olefins by Peracetic Acid and Hydrogen Peroxide Full article

Journal Advanced Synthesis and Catalysis
ISSN: 1615-4150 , E-ISSN: 1615-4169
Output data Year: 2011, Volume: 353, Number: 6, Pages: 885-889 Pages count : 5 DOI: 10.1002/adsc.201100030
Tags asymmetric oxidation, enzyme models, homogeneous catalysis, hydrogen peroxide, manganese
Authors Ottenbacher Roman V. 1,2 , Bryliakov Konstantin P. 1,2 , Talsi Evgenii P. 1,2
Affiliations
1 Boreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090, Russian Federation
2 Novosibirsk State University, Pirogova 2, Novosibirsk 630090, Russian Federation

Funding (1)

1 Russian Foundation for Basic Research 09-03-00087

Abstract: Chiral non-heme aminopyridine manganese complexes catalyze the enantioselective epoxidation of olefins with peracetic acid or hydrogen peroxide with moderate to high yields and ee valuess up to 89% (peracetic acid, AcOOH) and 84% (hydrogen peroxide, H2O2), performing as many as 1000 turnovers.
Cite: Ottenbacher R.V. , Bryliakov K.P. , Talsi E.P.
Non-Heme Manganese Complexes Catalyzed Asymmetric Epoxidation of Olefins by Peracetic Acid and Hydrogen Peroxide
Advanced Synthesis and Catalysis. 2011. V.353. N6. P.885-889. DOI: 10.1002/adsc.201100030 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Jan 13, 2011
Published online: Apr 14, 2011
Published print: Apr 18, 2011
Identifiers:
Web of science: WOS:000290613800013
Scopus: 2-s2.0-79955381023
Elibrary: 17001517
Chemical Abstracts: 2011:505540
Chemical Abstracts (print): 155:11643
OpenAlex: W2092934768
Citing:
DB Citing
Web of science 92
Scopus 98
Elibrary 96
OpenAlex 101
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