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Synthesis and Studies of Structured Support Ce0.75Zr0.25O2/θ-Al2O3/FeCrAl Full article

Journal Materials Letters
ISSN: 0167-577X , E-ISSN: 1873-4979
Output data Year: 2021, Volume: 283, Article number : 128855, Pages count : 4 DOI: 10.1016/j.matlet.2020.128855
Tags Adhesion; Alumina; Ce-Zr mixed oxide; Deposition; FeCrAlloy wire mesh; Structured catalysts
Authors Rogozhnikov V.N. 1,2 , Salanov A.N. 2 , Potemkin D.I. 2,3 , Glotov A.P. 1 , Boev S.V. 1 , Snytnikov P.V. 2,3
Affiliations
1 Gubkin Russian State University of Oil and Gas, Pr. Leninsky, 65, Moscow 119991, Russia
2 Boreskov Institute of Catalysis, Pr. Lavrentieva, 5, Novosibirsk 630090, Russia
3 Novosibirsk State University, Pirogova st., 2, Novosibirsk 630090, Russia

Funding (2)

1 Federal Agency for Scientific Organizations 0303-2016-0011
2 Russian Foundation for Basic Research 19-33-60057 (АААА-А20-120020490072-7)

Abstract: The procedure for preparing a structured composite system Ce0.75Zr0.25O2/θ-Al2O3/FeCrAl, which is used as a support for complete oxidation catalysts and catalysts for the conversion of liquid and gaseous hydrocarbons into synthesis gas, has been improved. The method for the synthesis of Ce0.75Zr0.25O2 powder has been optimized to facilitate its depositing on a FeCrAl mesh pre-coated by protective θ-Al2O3 layer. It has been shown by X-ray diffraction that the model powder sample and the cerium-zirconium mixed oxide coating on the alumina-precoated FeCrAl mesh have the same phase compositions. The protective layer of θ-Al2O3 on FeCrAl mesh possesses excellent adhesion properties that ensures high mechanical strength of the Ce0.75Zr0.25O2 coating under repeated heating–cooling cycles. The use of metal substrate as a component of the composite support provides high thermal conductivity, and thus reduces the formation of local hot spots under conditions of highly exothermic catalytic processes. © 2020 Elsevier B.V.
Cite: Rogozhnikov V.N. , Salanov A.N. , Potemkin D.I. , Glotov A.P. , Boev S.V. , Snytnikov P.V.
Synthesis and Studies of Structured Support Ce0.75Zr0.25O2/θ-Al2O3/FeCrAl
Materials Letters. 2021. V.283. 128855 :1-4. DOI: 10.1016/j.matlet.2020.128855 WOS Scopus РИНЦ AN OpenAlex
Dates:
Submitted: Aug 30, 2020
Accepted: Oct 13, 2020
Published online: Oct 19, 2020
Published print: Nov 15, 2021
Identifiers:
Web of science: WOS:000594709400024
Scopus: 2-s2.0-85093933978
Elibrary: 45199402
Chemical Abstracts: 2020:2159622
OpenAlex: W3092985609
Citing:
DB Citing
Scopus 4
Web of science 4
Elibrary 3
OpenAlex 5
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