Synthesis of Propylene Glycol Methyl Ether from Methanol and Propylene Oxide over Alumina-Pillared Clays | Sciact - CRIS-система Института катализа

Synthesis of Propylene Glycol Methyl Ether from Methanol and Propylene Oxide over Alumina-Pillared Clays Научная публикация

Журнал

Applied Catalysis B: Environmental
ISSN: 0926-3373 , E-ISSN: 1873-3883

Вых. Данные

Год: 2011, Том: 102, Номер: 3-4, Страницы: 433-440 Страниц : 8 DOI: 10.1016/j.apcatb.2010.12.020

Ключевые слова

Acid-base properties, Alumina pillared clay, Methanol, Propylene glycol methyl ether, Propylene oxide

Авторы

Timofeeva M.N. ¹ , Panchenko V.N. ¹ , Gil A. ² , Chesalov Yu.A. ¹ , Sorokina T.P. ³ , Likholobov V.A. ^1,4

Организации

1	Boreskov Institute of Catalysis SB RAS, Prospekt Akad. Lavrentieva 5, 630090 Novosibirsk, Russian Federation
2	Departamento de Quımica Aplicada, Universidad Publica de Navarra, Campus de Arrosadıa s/n, 31006 Pamplona, Spain
3	Institute of Hydrocarbons Processing SB RAS, Neftezavodskaya ul. 54, 644040 Omsk, Russian Federation
4	Omsk Scientific Centre SB RAS, Neftezavodskaya ul. 54, 644040 Omsk, Russian Federation

Информация о финансировании (1)

Российский фонд фундаментальных исследований

08-08-00729

Al-pillared interlayered clays (Al-PILCs) have been synthesized by the exchange reaction between Na-clay and Al-hydroxypolycation solutions aged for 0.5–14 days and characterized by DRS-UV–vis, XRD, FT-IR and N2-adsorption/desorption analyses, Hammett acidity titration with n-butylamine and FT-IR spectroscopy using PhCN and CDCl3 as probe molecules. It was found that the aging time of Al-hydroxypolycation pillaring solution affects both the textural characteristics and the physicochemical properties of Al-PILCs. Al-PILCs have been tested as catalysts for synthesis of propylene glycol methyl ether from methanol and propylene oxide. Increase in Al content due to the prolonged aging time favors the increase in the activity of Al-PILCs.

Timofeeva M.N. , Panchenko V.N. , Gil A. , Chesalov Y.A. , Sorokina T.P. , Likholobov V.A.
Synthesis of Propylene Glycol Methyl Ether from Methanol and Propylene Oxide over Alumina-Pillared Clays
Applied Catalysis B: Environmental. 2011. V.102. N3-4. P.433-440. DOI: 10.1016/j.apcatb.2010.12.020 WOS Scopus РИНЦ OpenAlex CAPlusCA

Поступила в редакцию:	27 окт. 2010 г.
Принята к публикации:	8 дек. 2010 г.
Опубликована online:	15 дек. 2010 г.
Опубликована в печати:	1 февр. 2011 г.

≡ Web of science:	WOS:000287946800010
≡ Scopus:	2-s2.0-79551526435
≡ РИНЦ:	16683535
≡ OpenAlex:	W2085642567
≡ Chemical Abstracts:	2011:158194
≡ Chemical Abstracts (print):	154:259975

≡ Web of science	36	Сбор данных от 06.02.2026
≡ Scopus	35	Сбор данных от 08.02.2026
≡ РИНЦ	36	Сбор данных от 08.02.2026
≡ OpenAlex	38	Сбор данных от 08.02.2026