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Zinc(II) and Manganese(II) Oxalatopalladates as Precursors of Bimetallic Nanomaterials Full article

Journal Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 , E-ISSN: 1531-8613
Output data Year: 2020, Volume: 65, Number: 10, Pages: 1571–1576 Pages count : 6 DOI: 10.1134/S003602362010006X
Tags palladium, thermogravimetry, photocatalysis, EXAFS
Authors Garkul’ I.A. 1 , Zadesenets A.V. 1 , Plyusnin P.E. 1 , Filatov E.Yu. 1 , Asanova T.I. 1 , Kozlov D.V. 2 , Korenev S.V. 1
Affiliations
1 Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
2 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia

Funding (1)

1 Russian Foundation for Basic Research 19-02-00308 (АААА-А19-119011590024-7)

Abstract: The thermal properties of [{Zn(H2O)3(PdOx2)}2(μ-H2O)2] · 4H2O and {(μ-Ox)Pd(μ-Ox)Mn(H2O)3}n · nH2O have been studied in various atmospheres. Zinc forms the intermetallide ZnPd in inert (He) and reductive (H2) atmospheres and a ZnO–PdO oxide mixture in an oxidative (air) atmosphere. Manganese forms MnO–Pd mixtures in an inert atmosphere, experiences deeper oxidation to Mn3O4 in an oxidative atmosphere, and is partially reduced to form the intermetallide Mn3Pd5 in a reductive atmosphere. High catalytic activity in CO photooxidation has been discovered in the Zn-containing sample deposited onto a TiO2 substrate. The XAFS spectroscopy data for the model catalysts make it possible to assume the formation of nanosized palladium particles during the hydrogen reduction of supported precursors.
Cite: Garkul’ I.A. , Zadesenets A.V. , Plyusnin P.E. , Filatov E.Y. , Asanova T.I. , Kozlov D.V. , Korenev S.V.
Zinc(II) and Manganese(II) Oxalatopalladates as Precursors of Bimetallic Nanomaterials
Russian Journal of Inorganic Chemistry. 2020. V.65. N10. P.1571–1576. DOI: 10.1134/S003602362010006X WOS Scopus РИНЦ AN OpenAlex
Original: Гаркуль И.А. , Задесенец А.В. , Плюснин П.Е. , Филатов Е.Ю. , Асанова Т.И. , Козлов Д.В. , Коренев С.В.
Оксалатопалладаты(II) цинка(II) и марганца(II) как предшественники биметаллических наноматериалов
Журнал неорганической химии. 2020. Т.65. №10. С.1371-1376. DOI: 10.31857/s0044457x20100062 РИНЦ OpenAlex
Dates:
Submitted: Apr 14, 2020
Accepted: May 27, 2020
Published print: Oct 1, 2020
Published online: Oct 30, 2020
Identifiers:
Web of science: WOS:000585519700015
Scopus: 2-s2.0-85094863701
Elibrary: 45182211
Chemical Abstracts: 2020:2257105
OpenAlex: W3095762058
Citing:
DB Citing
Scopus 9
Web of science 10
Elibrary 11
OpenAlex 10
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