Oxidation of Glucose and Arabinose Mixtures over Au/Al2O3 | Sciact - CRIS-система Института катализа

Oxidation of Glucose and Arabinose Mixtures over Au/Al2O3 Научная публикация

Журнал

Reaction Kinetics, Mechanisms and Catalysis
ISSN: 1878-5190 , E-ISSN: 1878-5204

Вых. Данные

Год: 2021, Том: 132, Номер: 1, Страницы: 59-72 Страниц : 14 DOI: 10.1007/s11144-020-01901-w

Ключевые слова

Sugar oxidation; Gold catalysts; Glucose; Arabinose; Kinetic modelling

Авторы

Franz Sebastian ¹ , Shcherban Nataliya D. ² , Simakova Irina L. ³ , Peurla Markus ⁴ , Eränen Kari ¹ , Wärnå Johan ¹ , Salmi Tapio ¹ , Murzin Dmitry Yu. ¹

Организации

1	Laboratory of Industrial Chemistry and Reaction Engineering, Johan Gadolin Process Chemistry Centre, Åbo Akademi University, Biskopsgatan 8, Abo, 20500 Turku, Finland
2	L.V. Pisarzhevsky Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 pr. Nauky, Kiev 03028, Ukraine
3	Boreskov Institute of Catalysis, Lavrentieva ave. 5, Novosibirsk, Russia 630090
4	University of Turku, 20500 Turku, Finland

Информация о финансировании (4)

1	Åbo Akademi University
2	Academy of Finland	319002
3	Национальная академия наук Украины	19/02-2020
4	Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)	ГЗ-2017-2020

Oxidation of a mixture of glucose and arabinose over 1% Au deposited on alumina was investigated in a semi-batch reactor varying pH, temperature and partial pressure of oxygen. Elevation of the latter enhancing the rate induced also losses in selectivity to aldonic acids. A kinetic model representing the catalytic oxidation reactions of arabinose and glucose along with respective isomerization to fructose and ribulose was developed. Calculations based on the model were able to describe experimental data in a reliable way.

Franz S. , Shcherban N.D. , Simakova I.L. , Peurla M. , Eränen K. , Wärnå J. , Salmi T. , Murzin D.Y.
Oxidation of Glucose and Arabinose Mixtures over Au/Al2O3

Reaction Kinetics, Mechanisms and Catalysis. 2021. V.132. N1. P.59-72. DOI: 10.1007/s11144-020-01901-w WOS Scopus РИНЦ CAPlus OpenAlex

Полный текст от издателя

Поступила в редакцию:	29 сент. 2020 г.
Принята к публикации:	24 окт. 2020 г.
Опубликована online:	2 нояб. 2020 г.
Опубликована в печати:	14 февр. 2021 г.

Web of science:	WOS:000583653100001
Scopus:	2-s2.0-85094810677
РИНЦ:	45219035
Chemical Abstracts:	2020:2256940
OpenAlex:	W3097179875

БД	Цитирований
Scopus	7
Web of science	8
РИНЦ	7
OpenAlex	9