Sciact
  • EN
  • RU

The Development of Metal-Carbon Catalysts for Oxidative Desulfurization of Diesel Fractions Научная публикация

Журнал Eurasian Chemico-Technological Journal
ISSN: 1562-3920
Вых. Данные Год: 2020, Том: 22, Номер: 2, Страницы: 81-88 Страниц : 8 DOI: 10.18321/ectj954
Ключевые слова Carbon nanomaterials, Metal nanoparticles, Catalyst, Oxidative desulfurization
Авторы Ismagilov Z.R. 1 , Matus E.V. 1 , Efimova O.S. 1 , Khitsova L.M. 1 , Popova A.N. 1 , Nikitin A.P. 1 , Sozinov S.A. 1
Организации
1 Federal Research Center of Coal and Coal Chemistry SB RAS, 18, Sovetsky ave., Kemerovo, Russia

Информация о финансировании (1)

1 Российский научный фонд 19-13-00129 (АААА-А19-119082990076-2)

Реферат: Metal-carbon materials M/CNTs (M = Ce, Сu, Mo) were synthesized by incipient wetness impregnation and their physicochemical characteristics were studied using various methods (inductively coupled plasma optical emission spectrometry, thermal analysis coupled with mass spectrometry, low-temperature nitrogen adsorption, X-ray diffraction and structural analysis, scanning electron microscopy, and Raman spectroscopy). It was found that M/CNTs (M = Ce, Сu, Mo) are the mesoporous materials consisting of carbon nanotubes with deposited СeO2, Сu2O/Cu or МоО3/MoO2 particles, respectively. The dispersion of supported species and their deposition uniformity improve in the series Сu < Се < Мо. The type of metal was shown to affect thermal stability as well as the textural and structural properties of the samples. The thermal stability of materials increases in the series Ce < Cu ≈ Mo, which is caused by different redox properties of the metals and also by the composition of products of the metal precursor decomposition. It is promising to use the developed materials as the catalysts for deep purification of diesel fraction components from sulfur compounds.
Библиографическая ссылка: Ismagilov Z.R. , Matus E.V. , Efimova O.S. , Khitsova L.M. , Popova A.N. , Nikitin A.P. , Sozinov S.A.
The Development of Metal-Carbon Catalysts for Oxidative Desulfurization of Diesel Fractions
Eurasian Chemico-Technological Journal. 2020. V.22. N2. P.81-88. DOI: 10.18321/ectj954 WOS Scopus РИНЦ CAPlus OpenAlex
Файлы: Полный текст от издателя
Даты:
Поступила в редакцию: 16 нояб. 2019 г.
Принята к публикации: 10 мар. 2020 г.
Опубликована в печати: 30 июн. 2020 г.
Опубликована online: 30 июн. 2020 г.
Идентификаторы БД:
Web of science: WOS:000558109200002
Scopus: 2-s2.0-85090642170
РИНЦ: 45340652
Chemical Abstracts: 2020:2672886
OpenAlex: W3048545243
Цитирование в БД:
БД Цитирований
Web of science 3
Scopus 4
OpenAlex 4
Альметрики: