Fe-Containing Nickel Phosphate Molecular Sieves as Heterogeneous Catalysts for Phenol Oxidation and Hydroxylation with H2O2 | Sciact - CRIS-система Института катализа

Fe-Containing Nickel Phosphate Molecular Sieves as Heterogeneous Catalysts for Phenol Oxidation and Hydroxylation with H2O2 Научная публикация

Журнал

Applied Catalysis B: Environmental
ISSN: 0926-3373 , E-ISSN: 1873-3883

Вых. Данные

Год: 2011, Том: 107, Номер: 1-2, Страницы: 197-204 Страниц : 8 DOI: 10.1016/j.apcatb.2011.07.014

Ключевые слова

Hydrogen peroxide, Hydroxylation, Nickel phosphate molecular sieves VSB-5, Oxidation, Phenol

Авторы

Timofeeva M.N. ¹ , Hasan Zubair ² , Orlov A.Yu. ^1,3 , Panchenko V.N. ¹ , Chesalov Yu.A. ¹ , Soshnikov I.E. ¹ , Jhung Sung Hwa ²

Организации

1	Boreskov Institute of Catalysis SB RAS, Prospekt Akad. Lavrentieva 5, 630090, Novosibirsk, Russian Federation
2	Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Sankyuck-Dong, Buk-Ku, Daegu 702-701, South Korea
3	Novosibirsk State University, st. Pirogova 2, 630090, Novosibirsk, Russian Federation

Информация о финансировании (1)

Korea Sanhak Foundation

Fe-containing nickel phosphate molecular sieves (Fe-VSB-5) were hydrothermally synthesized in weak basic conditions under microwave irradiation and characterized by SEM, XRD, N2-adsorption/desorption, DRS-UV–vis, and FT-IR spectroscopy using PhCN and CDCl3 as probe molecules. The catalytic activity of Fe-VSB-5 was tested for the phenol hydroxylation and wet phenol oxidation with H2O2. The increase in iron content in Fe-VSB-5 leds to an increase in the reaction rates. The increases in activity can be explained by the role of the Fe species, which increases the generation of radicals. The Fe-VSB-5 samples were stable against the leaching out of Fe ions. The catalytic activity of Fe-VSB-5 was compared to the catalytic activity of traditional Fe-containing materials.

Timofeeva M.N. , Hasan Z. , Orlov A.Y. , Panchenko V.N. , Chesalov Y.A. , Soshnikov I.E. , Jhung S.H.
Fe-Containing Nickel Phosphate Molecular Sieves as Heterogeneous Catalysts for Phenol Oxidation and Hydroxylation with H2O2
Applied Catalysis B: Environmental. 2011. V.107. N1-2. P.197-204. DOI: 10.1016/j.apcatb.2011.07.014 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	24 мая 2011 г.
Принята к публикации:	10 июл. 2011 г.
Опубликована online:	20 июл. 2011 г.
Опубликована в печати:	1 авг. 2011 г.

Web of science:	WOS:000294883300024
Scopus:	2-s2.0-80051468941
РИНЦ:	16997290
Chemical Abstracts:	2011:1023572
Chemical Abstracts (print):	155:355335
OpenAlex:	W1985217587

БД	Цитирований
Web of science	30
Scopus	30
РИНЦ	31
OpenAlex	31