Sciact
  • EN
  • RU

Method of Spectral Subtraction of Gas-Phase Fourier Transform Infrared (FT-IR) Spectra by Minimizing the Spectrum Length Научная публикация

Журнал Applied Spectroscopy
ISSN: 0003-7028 , E-ISSN: 1943-3530
Вых. Данные Год: 2011, Том: 65, Номер: 8, Страницы: 918-923 Страниц : 6 DOI: 10.1366/11-06281
Ключевые слова Fourier transform infrared spectroscopy, FT-IR spectroscopy, Long-path gas cell, Water vapor spectrum subtraction
Авторы Kozlov Denis 1 , Besov Alexey 1
Организации
1 Boreskov Institute of Catalysis, Novosibirsk 630090, Russian Federation

Информация о финансировании (3)

1 Сибирское отделение Российской академии наук 70
2 Совет по грантам Президента Российской Федерации НШ-3156.2010.3
3 Сибирское отделение Российской академии наук 36

Реферат: A new method of spectral subtraction for gas-phase Fourier transform infrared (FT-IR) spectra was developed for long-path gas measurements. The method is based on minimization of the length of the spectrum that results from subtracting the spectrum of an individual component of a gas mixture (water, CO(2), etc.) from the experimental spectrum of the mixture. For this purpose a subtraction coefficient (k(min)) is found for which the length of the resulting spectrum is minimized. A mathematical simulation with two Lorentzian absorption bands was conducted and the limits of application for the proposed method were determined. Two experimental examples demonstrate that a successful result could be achieved in the case when the subtrahend spectrum contains a number of narrow absorption bands (such as the spectrum of water vapor).
Библиографическая ссылка: Kozlov D. , Besov A.
Method of Spectral Subtraction of Gas-Phase Fourier Transform Infrared (FT-IR) Spectra by Minimizing the Spectrum Length
Applied Spectroscopy. 2011. V.65. N8. P.918-923. DOI: 10.1366/11-06281 WOS Scopus РИНЦ CAPlusCA PMID OpenAlex
Даты:
Поступила в редакцию: 25 февр. 2011 г.
Принята к публикации: 25 мая 2011 г.
Опубликована в печати: 1 авг. 2011 г.
Идентификаторы БД:
Web of science: WOS:000293206800011
Scopus: 2-s2.0-80051757900
РИНЦ: 18001978
Chemical Abstracts: 2011:993664
Chemical Abstracts (print): 156:91251
PMID (PubMed): 21819781
OpenAlex: W2135429672
Цитирование в БД:
БД Цитирований
Web of science 18
Scopus 19
РИНЦ 21
OpenAlex 19
Альметрики: