Investigation of Oxygen States and Reactivities on a Nanostructured Cupric Oxide Surface Научная публикация
| Журнал |
Applied Surface Science
ISSN: 0169-4332 |
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| Вых. Данные | Год: 2011, Том: 257, Номер: 20, Страницы: 8542-8549 Страниц : 8 DOI: 10.1016/j.apsusc.2011.05.012 | ||||
| Ключевые слова | CO oxidation, Copper (II) oxide, Nanoparticles, Oxygen species, RF discharge, STM, XPS | ||||
| Авторы |
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| Организации |
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Информация о финансировании (3)
| 1 | Российский фонд фундаментальных исследований | 10-03-00843 |
| 2 | Министерство образования и науки Российской Федерации | P-698 |
| 3 | Международный благотворительный научный фонд им. академика К.И. Замараева |
Реферат:
Nanostructured copper (II) oxide was formed on clean copper foil at room temperature using activated oxygen produced by RF discharge. CuO particles of approximately 10–20 nm were observed on the surface by Scanning Tunneling Microscopy (STM). The copper states and oxygen species of the model cupric oxide were studied by means of X-ray Photoelectron Spectroscopy (XPS). These oxide particles demonstrated abnormally high reactivity with carbon monoxide (CO) at temperatures below 100 °C. The XPS data showed that the interaction of CO with the nanostructured cupric oxide resulted in reduction of the CuO particles to Cu2O species. The reactivity of the nanostructured cupric oxide to CO was studied at 80 °C using XPS in step-by-step mode. The initial reactivity was estimated to be 5 × 10−5 and was steadily reduced down to 5 × 10−9 as the exposure was increased. O1s spectral analysis allowed us to propose that the high initial reactivity was caused by the presence of non-lattice oxygen states on the surface of the nanostructured CuO. We established that reoxidation of the partially reduced nanostructured cupric oxide by molecular oxygen O2 restored the highly reactive oxygen form on the surface. These results allowed us to propose that the nanostructured cupric oxide could be used for low temperature catalytic CO oxidation. Some hypotheses concerning the nature of the non-lattice oxygen species with high reactivity are also discussed.
Библиографическая ссылка:
Svintsitskiy D.A.
, Stadnichenko A.I.
, Demidov D.V.
, Koscheev S.V.
, Boronin A.I.
Investigation of Oxygen States and Reactivities on a Nanostructured Cupric Oxide Surface
Applied Surface Science. 2011. V.257. N20. P.8542-8549. DOI: 10.1016/j.apsusc.2011.05.012 WOS Scopus РИНЦ CAPlusCA OpenAlex
Investigation of Oxygen States and Reactivities on a Nanostructured Cupric Oxide Surface
Applied Surface Science. 2011. V.257. N20. P.8542-8549. DOI: 10.1016/j.apsusc.2011.05.012 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 30 дек. 2010 г. |
| Принята к публикации: | 3 мая 2011 г. |
| Опубликована online: | 11 мая 2011 г. |
| Опубликована в печати: | 1 авг. 2011 г. |
Идентификаторы БД:
| Web of science: | WOS:000291725100043 |
| Scopus: | 2-s2.0-80955177138 |
| РИНЦ: | 18013444 |
| Chemical Abstracts: | 2011:767130 |
| Chemical Abstracts (print): | 155:224611 |
| OpenAlex: | W2034789886 |