High-Resolution 3D Proton MRI of Hyperpolarized Gas Enabled by Parahydrogen and Rh/TiO2 Heterogeneous Catalyst | Sciact - CRIS-система Института катализа

High-Resolution 3D Proton MRI of Hyperpolarized Gas Enabled by Parahydrogen and Rh/TiO2 Heterogeneous Catalyst Научная публикация

Журнал

Chemistry - A European Journal
ISSN: 0947-6539 , E-ISSN: 1521-3765

Вых. Данные

Год: 2014, Том: 20, Номер: 37, Страницы: 11636-11639 Страниц : 4 DOI: 10.1002/chem.201403604, 10.1002/chem.201404052, 10.1002/chem.201490154

Ключевые слова

heterogeneous catalysis, hyperpolarized gas, magnetic resonance imaging, parahydrogen, supported catalysts

Авторы

Kovtunov Kirill V. ^1,2 , Barskiy Danila A. ^1,2 , Coffey Aaron M. ^3,4,5,6 , Truong Milton L. ^3,4,5,6 , Salnikov Oleg G. ^1,2 , Khudorozhkov Alexander K. ⁷ , Inozemtseva Elizaveta A. ⁷ , Prosvirin Igor P. ⁷ , Bukhtiyarov Valery I. ⁷ , Waddell Kevin W. ^3,4,5,6 , Chekmenev Eduard Y. ^3,4,5,6 , Koptyug Igor V. ^1,2

Организации

1	Laboratory of Magnetic Resonance Microimaging , International Tomography Center, SB RAS, 3A Institutskaya St., Novosibirsk 630090 (Russia)
2	Novosibirsk State University, 2 Pirogova St., Novosibirsk 630090 (Russia)
3	Institute of Imaging Science, Department of Radiology, Nashville, Tennessee, 37232-2310 (USA)
4	Department of Biomedical Engineering, Nashville, Tennessee, 37232-2310 (USA)
5	Department of Physics and Astronomy, Nashville, Tennessee, 37232-2310 (USA)
6	Department of Biochemistry, Nashville, Tennessee, 37232-2310 (USA)
7	Boreskov Institute of Catalysis SB RAS, 5 Acad. Lavrentiev Pr., Novosibirsk 630090 (Russia)

Информация о финансировании (14)

1	Федеральное агентство научных организаций России	V.45.3.2.
2	Российский фонд фундаментальных исследований	12-03-00403
3	Российский фонд фундаментальных исследований	14-03-00374
4	Российский фонд фундаментальных исследований	14-03-31239 (01201450183)
5	Сибирское отделение Российской академии наук	57
6	Сибирское отделение Российской академии наук	60
7	Сибирское отделение Российской академии наук	61
8	Сибирское отделение Российской академии наук	122
9	Президиум РАН	5.1.1
10	National Institutes of Health	3R00A134749-02S1
11	National Institutes of Health	5P50 CA128323-03
12	National Institutes of Health	R21 GM107947 5R00 CA134749-03
13	Совет по грантам Президента Российской Федерации	МК-4391.2013.3
14	United States Department of Defense	W81XWH-12-1-0159/BC112431

Several supported metal catalysts were synthesized, characterized, and tested in heterogeneous hydrogenation of propene with parahydrogen to maximize nuclear spin hyperpolarization of propane gas using parahydrogen induced polarization (PHIP). The Rh/TiO2 catalyst with a metal particle size of 1.6 nm was found to be the most active and effective in the pairwise hydrogen addition and robust, demonstrating reproducible results with multiple hydrogenation experiments and stability for ≥1.5 years. 3D (1) H magnetic resonance imaging (MRI) of 1 % hyperpolarized flowing gas with microscale spatial resolution (625×625×625 μm(3) ) and large imaging matrix (128×128×32) was demonstrated by using a preclinical 4.7 T scanner and 17.4 s imaging scan time.

Kovtunov K.V. , Barskiy D.A. , Coffey A.M. , Truong M.L. , Salnikov O.G. , Khudorozhkov A.K. , Inozemtseva E.A. , Prosvirin I.P. , Bukhtiyarov V.I. , Waddell K.W. , Chekmenev E.Y. , Koptyug I.V.
High-Resolution 3D Proton MRI of Hyperpolarized Gas Enabled by Parahydrogen and Rh/TiO2 Heterogeneous Catalyst

Chemistry - A European Journal. 2014. V.20. N37. P.11636-11639. DOI: 10.1002/chem.201403604, 10.1002/chem.201404052, 10.1002/chem.201490154 WOS Scopus РИНЦ CAPlusCA OpenAlex

Полный текст от издателя

Поступила в редакцию:	20 мая 2014 г.
Опубликована online:	24 июн. 2014 г.
Опубликована в печати:	8 сент. 2014 г.

Web of science:	WOS:000341630500003
Scopus:	2-s2.0-84906835041
РИНЦ:	23986904
Chemical Abstracts:	2014:1025894
Chemical Abstracts (print):	161:591726
OpenAlex:	W2052220397

БД	Цитирований
Web of science	74
Scopus	75
РИНЦ	73
OpenAlex	78