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Low-Temperature Oxidation of Isopropylbenzene Mediated by the System of NHPI, Fe(acac)3 and 1,10-phenanthroline Краткое сообщение

Журнал Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905
Вых. Данные Год: 2021, Том: 149, Номер статьи : 106218, Страниц : 5 DOI: 10.1016/j.catcom.2020.106218
Ключевые слова Oxidation; Isopropylbenzene; N-Hydroxyphthalimide; Iron(III) acetylacetonate; 1,10-Phenantroline; Isopropylbenzene hydroperoxide
Авторы Kuznetsova N.I. 1 , Babushkin D.E. 1 , Zudin V.N. 1 , Koscheeva O.S. 2 , Kuznetsova L.I. 1
Организации
1 Boreskov Institute of Catalysis SB RAS, 5 Prospekt Lavrentieva, Novosibirsk 630090, RF
2 Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Prospect Lavrentueva, Novosibirsk 630090, RF

Информация о финансировании (2)

1 Федеральное агентство научных организаций России 0303-2016-0006 (V.44.1.6)
2 Российский фонд фундаментальных исследований 19-43-540008

Реферат: Highly efficient oxidation of isopropylbenzene mediated by the system of NHPI/Fe(acac)3/Phen has been carried out at temperature as low as 60 °C. Significant improvement of catalysis by NHPI was associated with an enhanced oxidizing ability of Fe(III) tandem with Phen, which caused the intense generation of PINO. Furthermore, NMR observations revealed formation of a hydrogen-bonded NHPI-Phen adduct soluble in acetonitrile and isopropylbenzene. Based on this phenomenon, the system was applicable for the oxidation of solvent-free isopropylbenzene. The promise of the system of NHPI/Fe(acac)3/Phen for the selective synthesis of isopropylbenzene hydroperoxide was demonstrated by oxidation at a low content of Fe(acac)3.
Библиографическая ссылка: Kuznetsova N.I. , Babushkin D.E. , Zudin V.N. , Koscheeva O.S. , Kuznetsova L.I.
Low-Temperature Oxidation of Isopropylbenzene Mediated by the System of NHPI, Fe(acac)3 and 1,10-phenanthroline
Catalysis Communications. 2021. V.149. 106218 :1-5. DOI: 10.1016/j.catcom.2020.106218 WOS Scopus РИНЦ CAPlusCA OpenAlex
Файлы: Полный текст от издателя
Даты:
Поступила в редакцию: 8 сент. 2020 г.
Принята к публикации: 30 окт. 2020 г.
Опубликована online: 5 нояб. 2020 г.
Опубликована в печати: 15 янв. 2021 г.
Идентификаторы БД:
Web of science: WOS:000600589400031
Scopus: 2-s2.0-85096119738
РИНЦ: 45144522
Chemical Abstracts: 2020:2438783
Chemical Abstracts (print): 174:11347
OpenAlex: W3095393572
Цитирование в БД:
БД Цитирований
Scopus 21
Web of science 17
РИНЦ 22
OpenAlex 24
Альметрики: