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A New Insight into Cobalt Metal Powder Internal Field 59Co NMR Spectra Full article

Journal Applied Magnetic Resonance
ISSN: 0937-9347 , E-ISSN: 1613-7507
Output data Year: 2014, Volume: 45, Number: 10, Pages: 1009-1017 Pages count : 9 DOI: 10.1007/s00723-014-0580-0
Tags Cobalt; Domain walls; Ferromagnetism; Nuclear magnetic resonance; Nuclear magnetic resonance spectroscopy; Powder metals
Authors Andreev A.S. 1,2 , Lapina O.B. 1,2 , Cherepanova S.V. 1,2
Affiliations
1 Boreskov Institute of Catalysis SB RAS (BIC SB RAS), pr. Lavrentieva, 5, 630090 Novosibirsk, Russia
2 Novosibirsk State University (NSU), Pirogova str., 2, 630090 Novosibirsk, Russia

Funding (6)

1 Russian Foundation for Basic Research 13-03-00482
2 Russian Foundation for Basic Research 14-03-31684
3 Russian Foundation for Basic Research 15-53-15035
4 The Ministry of Education and Science of the Russian Federation
5 French Embassy in Moscow
6 Council for Grants of the President of the Russian Federation СП-389.2012.1

Abstract: The authors present a new approach of internal field 59Co NMR spectra assignment leaving apart from “usual” decomposition on “pure” hcp and fcc stackings, and a set of stacking faults (sfs) sf1–sf5 with a certain lines position. The authors propose including into consideration not only cobalt structural features as well as its magnetic nature due to the strong ferromagnetism in Co metal. The last fact supposes an existence of different magnetic species such as magnetic domains, domain walls, and single-domain particles, thereby helping to spectral lines assignment according to both structural and magnetic origin. The examined sample contains fcc and hcp resonance peaks in both domains and domain walls giving the hcp to fcc ratio equal to 1.9, as well a significant amount of Co sfs, or Co in loose coordination, up to 10 %. The research exhibits a good agreement of all implemented techniques.
Cite: Andreev A.S. , Lapina O.B. , Cherepanova S.V.
A New Insight into Cobalt Metal Powder Internal Field 59Co NMR Spectra
Applied Magnetic Resonance. 2014. V.45. N10. P.1009-1017. DOI: 10.1007/s00723-014-0580-0 WOS Scopus РИНЦ AN OpenAlex
Dates:
Submitted: Jul 1, 2014
Published online: Aug 28, 2014
Published print: Oct 1, 2014
Identifiers:
Web of science: WOS:000344058800005
Scopus: 2-s2.0-84919442453
Elibrary: 24020613
Chemical Abstracts: 2014:1453710
OpenAlex: W1978815200
Citing:
DB Citing
Web of science 15
Scopus 16
Elibrary 15
OpenAlex 17
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