Technologies for Simultaneous Low-Temperature Catalytic Removal of NOх and N2O from the Tail Gases of Nitric Acid Plants Full article
| Journal |
Chemistry for Sustainable Development
ISSN: 1817-1818 |
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| Output data | Year: 2020, Volume: 28, Number: 2, Pages: 203-212 Pages count : 10 DOI: 10.15372/CSD2020221 | ||
| Tags | nitric oxide, nitrous oxide, simultaneous removal, catalysts for SCR, catalysts for low-temperature destruction of nitrous oxide, nitric acid plants | ||
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| Affiliations |
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Funding (1)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0017 |
Abstract:
The reasons for the formation of nitrous oxide (a greenhouse gas with CO2-equivalent equal to 310) at modern plants manufacturing weak nitric acid are analyzed. The amount of annual N2O emission depending on the operating conditions of the ammonia converter and on the method of the removal of nitrogen oxides NOх is estimated. A technological scheme of simultaneous low-temperature removal of NOx and N2O from exhaust tail gases is proposed, in which V/Al catalyst for the selective catalytic reduction (SCR) of NOx with ammonia and Сs/Co3O4 catalyst for N2O decomposition are used. Mathematical modeling of a 2-layer catalytic reactor is carried out; the charges of both SCR catalyst and N2O decomposition catalyst are determined, which ensures compliance with environmental emission standards for all nitrogen oxides.
Cite:
Chumachenko V.A.
, Isupova L.A.
, Ivanova Y.A.
, Ovchinnikova E.V.
, Reshetnikov S.I.
, Noskov A.S.
Technologies for Simultaneous Low-Temperature Catalytic Removal of NOх and N2O from the Tail Gases of Nitric Acid Plants
Chemistry for Sustainable Development. 2020. V.28. N2. P.203-212. DOI: 10.15372/CSD2020221 WOS РИНЦ OpenAlex
Technologies for Simultaneous Low-Temperature Catalytic Removal of NOх and N2O from the Tail Gases of Nitric Acid Plants
Chemistry for Sustainable Development. 2020. V.28. N2. P.203-212. DOI: 10.15372/CSD2020221 WOS РИНЦ OpenAlex
Original:
Чумаченко В.А.
, Исупова Л.А.
, Иванова Ю.А.
, Овчинникова Е.В.
, Решетников С.И.
, Носков А.С.
Технологии комплексной низкотемпературной каталитической очистки промышленных газовых выбросов от NOх и N2O в производстве азотной кислоты
Химия в интересах устойчивого развития. 2020. Т.28. №2. С.210-219. DOI: 10.15372/KhUR2020221RSCI РИНЦ AN OpenAlex
Технологии комплексной низкотемпературной каталитической очистки промышленных газовых выбросов от NOх и N2O в производстве азотной кислоты
Химия в интересах устойчивого развития. 2020. Т.28. №2. С.210-219. DOI: 10.15372/KhUR2020221RSCI РИНЦ AN OpenAlex
Identifiers:
| Web of science: | WOS:000587496600013 |
| Elibrary: | 47497023 |
| OpenAlex: | W4251113230 |