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Which Species, Zn2+ Cations or ZnO Clusters, Are More Efficient for Olefin Aromatization? 13C Solid-State NMR Investigation of n-But-1-ene Transformation on Zn-Modified Zeolite Full article

Journal ACS Catalysis
ISSN: 2155-5435
Output data Year: 2020, Volume: 10, Number: 23, Pages: 14224-14233 Pages count : 10 DOI: 10.1021/acscatal.0c03647
Tags BEA zeolite, zinc, n-butene, oligomerization, aromatization, solid-state NMR, DFT
Authors Lashchinskaya Zoya N. 1,2 , Gabrienko Anton A. 1,2 , Arzumanov Sergei S. 1,2 , Kolganov Alexander A. 1 , Toktarev Alexander V. 1 , Freude Dieter 3 , Haase Jürgen 3 , Stepanov Alexander G. 1,2
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090, Russia
2 Faculty of Natural Sciences, Department of Physical Chemistry, Novosibirsk State University, Novosibirsk 630090, Russia
3 Fakultät für Physik und Geowissenschaften, Universität Leipzig, 04103 Leipzig, Germany

Funding (2)

1 Russian Science Foundation
German Research Foundation
19-43-04101
2 German Research Foundation HA 1893/22-1

Abstract: The analysis of n-but-1-ene transformation on Zn-modified zeolite H-BEA, containing zinc exclusively in the form of either Zn2+ cations (Zn2+/H-BEA sample) or small clusters of ZnO (ZnO/H-BEA sample), has been performed with 13C solid-state nuclear magnetic resonance (NMR) at 296–673 K. The number of intermediates, including π-complex of n-but-2-ene, methylallylzinc, and delocalized carbanionic species formed by the interaction of oligomeric polyenes with Zn sites, have been identified for both zeolite samples. Methyl-substituted cyclopentenyl cation and cyclohexadienyl cation are additionally identified for the reaction on ZnO/H-BEA. It is inferred that the aromatization of the olefin occurs basically with the involvement of Zn2+ sites on Zn2+/H-BEA. For ZnO/H-BEA, besides aromatization with the assistance of ZnO species, conjunct polymerization process with the involvement of Brønsted acid sites (BAS) contributes notably to the olefin aromatization. The latter process affords also some quantity of C1–C4 alkanes. It is concluded that the stronger interaction of the olefin (confirmed by density functional theory (DFT) calculations) and oligomeric polyenes with Zn2+ cations than with ZnO species and different quantities of BAS for two zeolite samples provide peculiar performances of Zn2+/H-BEA and ZnO/H-BEA zeolites for the olefin aromatization. Based on careful analysis of the obtained spectroscopic results, it is suggested that Zn-modified zeolite containing Zn2+ cationic species and some quantity of BAS should exhibit higher efficiency as the catalyst for small olefin and alkane aromatization compared to the zeolite with ZnO species and high concentration of BAS.
Cite: Lashchinskaya Z.N. , Gabrienko A.A. , Arzumanov S.S. , Kolganov A.A. , Toktarev A.V. , Freude D. , Haase J. , Stepanov A.G.
Which Species, Zn2+ Cations or ZnO Clusters, Are More Efficient for Olefin Aromatization? 13C Solid-State NMR Investigation of n-But-1-ene Transformation on Zn-Modified Zeolite
ACS Catalysis. 2020. V.10. N23. P.14224-14233. DOI: 10.1021/acscatal.0c03647 WOS Scopus РИНЦ AN OpenAlex
Dates:
Submitted: Aug 20, 2020
Accepted: Oct 23, 2020
Published online: Nov 20, 2020
Published print: Dec 4, 2020
Identifiers:
Web of science: WOS:000598140200040
Scopus: 2-s2.0-85097763936
Elibrary: 45078672
Chemical Abstracts: 2020:2403410
OpenAlex: W3109047774
Citing:
DB Citing
Scopus 39
Web of science 37
Elibrary 37
OpenAlex 36
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