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Influence of Oligomeric Unsaturated Polyketone on the Vulcanization of Elastomeric Compositions in the Presence of Sulfenamide C Full article

Journal Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171
Output data Year: 2020, Volume: 69, Number: 11, Pages: 2171-2176 Pages count : 6 DOI: 10.1007/s11172-020-3018-x
Tags vulcanization, polyketone, rubber, sulfenamide C.
Authors Voronchihin V.D. 1 , Sorochenko O.V. 1 , Semikolenov S.V. 2 , Ivanov D.P. 2 , Babushkin D.E. 2 , Dubkov K.A. 2
Affiliations
1 M.F. Reshetnev Siberian State University of Science and Technology, 31 prosp. Gazety Krasnoyarsky Rabochy, 660037 Krasnoyarsk, Russia Federation
2 Federal Research Center G.K.Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 prosp. Akad. Lavrentieva, 630090 Novosibirsk, Russia Federation

Funding (2)

1 Federal Agency for Scientific Organizations 0303-2016-0006 (V.44.1.6)
2 Russian Foundation for Basic Research 17-03-00706

Abstract: Effect of the oligomeric unsaturated polyketone (UPK) additive on the rheological properties, vulcanization, and structural characteristics of elastomeric compositions based on butadiene and nitrile-butadiene rubbers containing N-cyclohexyl-2-benzothiazolylsulfenamide (sulfenamide C) as vulcanizing accelerator is investigated. It was demonstrated using IR and NMR spectroscopy that sulfenamide C reacts with polyketone. A mechanism for such interaction, which includes the sequential addition of benzothiazyl sulfide and amine fragments to the oligomeric chain, was proposed.
Cite: Voronchihin V.D. , Sorochenko O.V. , Semikolenov S.V. , Ivanov D.P. , Babushkin D.E. , Dubkov K.A.
Influence of Oligomeric Unsaturated Polyketone on the Vulcanization of Elastomeric Compositions in the Presence of Sulfenamide C
Russian Chemical Bulletin. 2020. V.69. N11. P.2171-2176. DOI: 10.1007/s11172-020-3018-x WOS Scopus РИНЦ ANCAN OpenAlex
Original: Ворончихин В.Д. , Сороченко О.В. , Семиколенов С.В. , Иванов Д.П. , Бабушкин Д.Э. , Дубков К.А.
Влияние олигомерного ненасыщенного поликетона на вулканизацию эластомерных композиций в присутствии сульфенамида Ц
Известия Академии наук. Серия химическая. 2020. №11. С.2171-2176. РИНЦ
Dates:
Submitted: May 20, 2019
Accepted: Aug 20, 2020
Published print: Nov 1, 2020
Published online: Dec 4, 2020
Identifiers:
Web of science: WOS:000596085400020
Scopus: 2-s2.0-85097080088
Elibrary: 45107253
Chemical Abstracts: 2020:2503658
Chemical Abstracts (print): 174:171552
OpenAlex: W3112269163
Citing: Пока нет цитирований
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