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Guaiacol Hydrodeoxygenation in the Presence of Ni-Containing Catalysts Full article

Journal Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555
Output data Year: 2011, Volume: 3, Number: 1, Pages: 15-22 Pages count : 8 DOI: 10.1134/S2070050411010028
Tags biomass, guaiacol, hydrodeoxygenation, Ni-containing catalysts, pyrolysis, sol-gel method
Authors Bykova M.V. 1 , Bulavchenko O.A. 2 , Ermakov D.Y. 2 , Lebedev M.Y. 2 , Yakovlev V.A. 2 , Parmon V.N. 2
Affiliations
1 Novosibirsk State University, Novosibirsk, 630090 Russia
2 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy

Funding (3)

1 The Ministry of Education and Science of the Russian Federation 02.513.11.3482
2 The Ministry of Education and Science of the Russian Federation 02.526.11.6007
3 The Ministry of Education and Science of the Russian Federation NK-150P

Abstract: A series of Ni-containing catalysts supported on different materials has been tested in the hydrodeoxygenation of guaiacol, a compound modeling the products of biomass fast pyrolysis. The reaction has been carried out in an autoclave at 320°C and a hydrogen pressure of 17 MPa. The main guaiacol hydrodeoxygenation products are cyclohexane, 1-methylcyclohexane-1,2-diol, and cyclohexanone (which result from aromatic ring reduction). A guaiacol conversion scheme explaining the formation of the main products is suggested. The highest activity is shown by the Ni-containing catalysts on SiO2 and SiO2-ZrO2 supports prepared by the sol-gel method. According to X-ray diffraction and electron microscopic data, the high activity of these catalysts is due to the high concentration of dispersed nickel as reduced films on the surface of the silicate structures. The catalysts offer promise for refining the biomass fast pyrolysis products (bio-oil) into hydrocarbon fuel.
Cite: Bykova M.V. , Bulavchenko O.A. , Ermakov D.Y. , Lebedev M.Y. , Yakovlev V.A. , Parmon V.N.
Guaiacol Hydrodeoxygenation in the Presence of Ni-Containing Catalysts
Catalysis in Industry. 2011. V.3. N1. P.15-22. DOI: 10.1134/S2070050411010028 WOS Scopus РИНЦ OpenAlex
Original: Быкова М.В. , Булавченко О.А. , Ермаков Д.Ю. , Лебедев М.Ю. , Яковлев В.А. , Пармон В.Н.
Гидродеоксигенация гваякола в присутствии Ni-содержащих катализаторов
Катализ в промышленности. 2010. №5. С.45-52. РИНЦ ANCAN
Dates:
Submitted: Jul 20, 2010
Published print: Mar 1, 2011
Published online: Apr 26, 2011
Identifiers:
Web of science: WOS:000433658900004
Scopus: 2-s2.0-79956213138
Elibrary: 16987771
OpenAlex: W2002812279
Citing:
DB Citing
Scopus 53
Elibrary 56
OpenAlex 60
Web of science 51
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