Analysis of the Molecular Structure of Ethylene Hexene-1 Copolymers Produced over Highly Active Supported Ziegler-Natta Catalysts Full article
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Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555 |
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| Output data | Year: 2011, Volume: 3, Number: 2, Pages: 109-115 Pages count : 7 DOI: 10.1134/S2070050411020097 | ||
| Tags | Differential scanning calorimetry, Ethylene hexene-1 copolymer, Fractionation, Gel permeation chromatography, Molecular structure, Molecular weight distribution, Polyethylene, Ti-Mg catalyst, V-Mg catalyst, Ziegler-Natta catalyst | ||
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Abstract:
The mechanical and rheological properties of ethylene α-olefin copolymers are governed by a molecular and supramolecular structure that depends on its molecular weight characteristics, comonomer concentration, and the uniformity of branching distributions for polymer chains with different molecular weights (compositional heterogeneity). Using state-of-the-art methods, we study the parameters of molecular weight distribution, molecular structure, and compositional heterogeneity of ethylene hexene-1 copolymers with different compositions, produced over highly active supported Ti-Mg and V-Mg Ziegler-Natta catalysts, and show the possibility of controlling these parameters to improve the quality of the resulting polymers.
Cite:
Matsko M.A.
, Echevskaya L.G.
, Mikenas T.B.
, Nikolaeva M.I.
, Vanina M.P.
, Zakharov V.A.
Analysis of the Molecular Structure of Ethylene Hexene-1 Copolymers Produced over Highly Active Supported Ziegler-Natta Catalysts
Catalysis in Industry. 2011. V.3. N2. P.109-115. DOI: 10.1134/S2070050411020097 WOS Scopus РИНЦ OpenAlex
Analysis of the Molecular Structure of Ethylene Hexene-1 Copolymers Produced over Highly Active Supported Ziegler-Natta Catalysts
Catalysis in Industry. 2011. V.3. N2. P.109-115. DOI: 10.1134/S2070050411020097 WOS Scopus РИНЦ OpenAlex
Original:
Мацько М.А.
, Ечевская Л.Г.
, Микенас Т.Б.
, Николаева М.И.
, Ванина М.П.
, Захаров В.А.
Анализ и регулирование молекулярной структуры сополимеров этилена с гексеном-1, полученных на высокоактивных нанесенных катализаторах Циглера-Натта
Катализ в промышленности. 2011. №1. С.20-25. РИНЦ ANCAN
Анализ и регулирование молекулярной структуры сополимеров этилена с гексеном-1, полученных на высокоактивных нанесенных катализаторах Циглера-Натта
Катализ в промышленности. 2011. №1. С.20-25. РИНЦ ANCAN
Dates:
| Submitted: | Nov 29, 2010 |
| Published print: | Jun 1, 2011 |
| Published online: | Jul 19, 2011 |
Identifiers:
| Web of science: | WOS:000433659100002 |
| Scopus: | 2-s2.0-80755125518 |
| Elibrary: | 18012624 |
| OpenAlex: | W2019720324 |