Tungsten Peroxopolyoxo Complexes are Prospective Catalysts for the Oxidation of Organic Compounds. I. Structure of Complex [(Bun)4N]3{PO4[WO(O2)2]4} According to Small-Angle X-Ray Scattering Full article
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Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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| Output data | Year: 2020, Volume: 61, Number: 10, Pages: 1568–1574 Pages count : 7 DOI: 10.1134/S002247662010008X | ||
| Tags | metal complexes, peroxopolyoxotungstates, quaternary ammonium compounds, small-angle X-ray scattering | ||
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| Affiliations |
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Funding (3)
| 1 | Russian Foundation for Basic Research | 19-03-00202 |
| 2 | Federal Agency for Scientific Organizations | 0303-2016-0008 |
| 3 | Federal Agency for Scientific Organizations | 0303-2016-0002 |
Abstract:
The structure of the H3PW12O40 oxometalate precursor and that of the [(Bun)4N]3{PO4[WO(O2)2]4} peroxo complex which was synthesized from it are studied by small-angle X-ray scattering (SAXS) in solutions. It is shown that the structure of H3PW12O40 is partially destroyed as a result of the interaction with hydrogen peroxide to form the {PO4[WO(O2)2]4}3– anion. The synthesized peroxo complex [(Bun)4N]3{PO4[WO(O2)2]4} in toluene occurs as individual molecules, whereas its molecules are partially aggregated to form 1.6 nm particles in acetonitrile solution.
Cite:
Larichev Y.V.
, Selivanova N.V.
, Berdnikova P.V.
, Tuzikov F.V.
, Pai Z.P.
Tungsten Peroxopolyoxo Complexes are Prospective Catalysts for the Oxidation of Organic Compounds. I. Structure of Complex [(Bun)4N]3{PO4[WO(O2)2]4} According to Small-Angle X-Ray Scattering
Journal of Structural Chemistry. 2020. V.61. N10. P.1568–1574. DOI: 10.1134/S002247662010008X WOS Scopus РИНЦ AN OpenAlex
Tungsten Peroxopolyoxo Complexes are Prospective Catalysts for the Oxidation of Organic Compounds. I. Structure of Complex [(Bun)4N]3{PO4[WO(O2)2]4} According to Small-Angle X-Ray Scattering
Journal of Structural Chemistry. 2020. V.61. N10. P.1568–1574. DOI: 10.1134/S002247662010008X WOS Scopus РИНЦ AN OpenAlex
Original:
Ларичев Ю.В.
, Селиванова Н.В.
, Бердникова П.В.
, Тузиков Ф.В.
, Пай З.П.
Пероксополиоксокомплексы вольфрама – перспективные катализаторы окисления органических соединений. I. Структура комплекса [(n-Bu)4N]3{PO4[WO(O2)2]4} по данным метода малоуглового рентгеновского рассеяния
Журнал структурной химии. 2020. Т.61. №10. С.1652-1658. DOI: 10.26902/JSC_id61833RSCI РИНЦ OpenAlex
Пероксополиоксокомплексы вольфрама – перспективные катализаторы окисления органических соединений. I. Структура комплекса [(n-Bu)4N]3{PO4[WO(O2)2]4} по данным метода малоуглового рентгеновского рассеяния
Журнал структурной химии. 2020. Т.61. №10. С.1652-1658. DOI: 10.26902/JSC_id61833RSCI РИНЦ OpenAlex
Dates:
| Submitted: | Dec 12, 2019 |
| Accepted: | Apr 30, 2020 |
| Published print: | Oct 13, 2020 |
| Published online: | Oct 13, 2020 |
Identifiers:
| Web of science: | WOS:000598775100008 |
| Scopus: | 2-s2.0-85106791626 |
| Elibrary: | 46778310 |
| Chemical Abstracts: | 2020:2612542 |
| OpenAlex: | W3112343347 |