Tuning Pt Characteristics on Pt/C Catalyst for Aqueous-Phase Reforming of Biomass-Derived Oxygenates to bio-H2 | Sciact - CRIS-система Института катализа

Tuning Pt Characteristics on Pt/C Catalyst for Aqueous-Phase Reforming of Biomass-Derived Oxygenates to bio-H2 Научная публикация

Журнал

Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875

Вых. Данные

Год: 2021, Том: 610, Номер статьи : 117963, Страниц : 11 DOI: 10.1016/j.apcata.2020.117963

Ключевые слова

APR; Renewable; Ethylene glycol; Pt particle; Pt distribution

Авторы

Vikla A.K.K. ^1,5 , Simakova I. ² , Demidova Y. ² , Keim E.G. ³ , Calvo L. ⁴ , Gilarranz M.A. ⁴ , He Songbo ^1,6 , Seshan K. ¹

Организации

1	Faculty of Science and Technology, University of Twente
2	Boreskov Institute of Catalysis
3	University of Twente, MESA+ NanoLab
4	Department of Chemical Engineering
5	Biomass Technology Group BV
6	Green Chemical Reaction Engineering, Engineering and Technology Institute Groningen, University of Groningen

Информация о финансировании (2)

1	European Commission	310490 FP7-NMP-2012-SMALL-6 SUSFUELCAT
2	Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)	ГЗ-2017-2020

Pt/C catalysts with varied Pt sizes and distributions were investigated for aqueous-phase reforming (APR) of ethylene glycol (EG) to H2. APR experiments were performed on a continuous-flow fixed bed reactor with a catalyst loading of 1 g and EG feeding of 120 mL h−1 at 225 °C and 35 bar for 7 h. The fresh and used Pt/C catalysts were characterized by XRF, BET, CO chemisorption, TEM, XTEM, and XPS. Catalyst preparation protocols changed Pt characteristics on Pt/C catalysts, leading to a distinguishable H2 production. The rates for EG conversion and H2 production increased linearly with mean Pt size (3–11 nm), while having a volcano relationship with the mean size of agglomerated Pt particles (17–30 nm). Pt with concentrated Pt particles on surface of Pt/C catalysts was more preferable for APR of EG than the homogeneously distributed in catalysts. Optimal performance was obtained over a Pt/C-PR catalyst, which was prepared by precipitation method, showing a superb turnover frequency of 248 molH2 molPt−1 min−1 for H2 production from EG in APR. Besides, Pt/C catalysts also showed excellent stability. These results have shown the promise of Pt/C catalyst for APR of EG, which can be extended for bio-H2 production via APR of biomass-derived oxygenates in waste streams.

Vikla A.K.K. , Simakova I. , Demidova Y. , Keim E.G. , Calvo L. , Gilarranz M.A. , He S. , Seshan K.
Tuning Pt Characteristics on Pt/C Catalyst for Aqueous-Phase Reforming of Biomass-Derived Oxygenates to bio-H2

Applied Catalysis A: General. 2021. V.610. 117963 :1-11. DOI: 10.1016/j.apcata.2020.117963 WOS Scopus РИНЦ CAPlus OpenAlex

Полный текст от издателя

Поступила в редакцию:	22 сент. 2020 г.
Принята к публикации:	6 дек. 2020 г.
Опубликована online:	11 дек. 2020 г.
Опубликована в печати:	25 янв. 2021 г.

Web of science:	WOS:000613265700006
Scopus:	2-s2.0-85098470422
РИНЦ:	45049990
Chemical Abstracts:	2020:2692745
OpenAlex:	W3111786345

БД	Цитирований
Scopus	11
Web of science	12
РИНЦ	10
OpenAlex	13