Formation of Effective Copper-Based Catalysts of Methanol Synthesis Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
||
|---|---|---|---|
| Output data | Year: 2020, Volume: 61, Number: 6, Pages: 886-893 Pages count : 8 DOI: 10.1134/S0023158420060087 | ||
| Tags | Cu-based catalysts; methanol synthesis, aurichalcite, malachite | ||
| Authors |
|
||
| Affiliations |
|
Funding (1)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0013 |
Abstract:
Abstract: The regularities of formation of the composition and structure of a highly efficient catalyst for methanol synthesis have been revealed. The catalyst was obtained by thermal treatment of the combined CuZnAl(Cr) hydroxocarbonate followed by the reductive activation of the anion-modified zinc oxide precursor. The composition and structure of hydroxocarbonate are determined by the nature of components and their ratio. The thermal decomposition of hydroxocarbonates at 550–650 K formed the oxide catalyst; at higher temperatures, the product was an inactive mixture of oxides. The oxide catalyst is mixed zinc oxide containing the Cu2+ and Al or Cr3+ cations and residual (СО3)2– and ОН– anions, i.e., the anion-modified oxide. © 2020, Pleiades Publishing, Ltd.
Cite:
Minyukova T.P.
, Khassin A.A.
, Khasin A.V.
, Yurieva T.M.
Formation of Effective Copper-Based Catalysts of Methanol Synthesis
Kinetics and Catalysis. 2020. V.61. N6. P.886-893. DOI: 10.1134/S0023158420060087 WOS Scopus РИНЦ AN OpenAlex
Formation of Effective Copper-Based Catalysts of Methanol Synthesis
Kinetics and Catalysis. 2020. V.61. N6. P.886-893. DOI: 10.1134/S0023158420060087 WOS Scopus РИНЦ AN OpenAlex
Original:
Минюкова Т.П.
, Хасин А.А.
, Хасин А.В.
, Юрьева Т.М.
Закономерности формирования эффективных медьсодержащих катализаторов синтеза метанола
Кинетика и катализ. 2020. Т.61. №6. С.855-863. DOI: 10.31857/S045388112006009XRSCI РИНЦ OpenAlex
Закономерности формирования эффективных медьсодержащих катализаторов синтеза метанола
Кинетика и катализ. 2020. Т.61. №6. С.855-863. DOI: 10.31857/S045388112006009XRSCI РИНЦ OpenAlex
Dates:
| Submitted: | Feb 10, 2020 |
| Accepted: | May 8, 2020 |
| Published print: | Nov 1, 2020 |
| Published online: | Dec 28, 2020 |
Identifiers:
| Web of science: | WOS:000603310400008 |
| Scopus: | 2-s2.0-85098239785 |
| Elibrary: | 45050029 |
| Chemical Abstracts: | 2021:19455 |
| OpenAlex: | W3113514946 |