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Room Temperature Interaction of NO2 with Palladium Nanoparticles Supported on a Nonactivated Surface of Highly Oriented Pyrolytic Graphite (HOPG) Full article

Journal Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Output data Year: 2020, Volume: 61, Number: 6, Pages: 907-911 Pages count : 5 DOI: 10.1134/S0023158420060142
Tags highly oriented pyrolytic graphite (HOPG); NO2; palladium; platinum; X-ray photoelectron spectroscopy
Authors Smirnov M.Yu. 1 , Kalinkin A.V. 1 , Sorokin A.M. 1 , Bukhtiyarov V.I. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia

Funding (1)

1 Federal Agency for Scientific Organizations 0303-2016-0001

Abstract: Abstract: A sample of palladium nanoparticles with an average size of ~5 nm on the surface of highly oriented pyrolytic graphite (HOPG) was prepared by vacuum deposition. With the use of X-ray photoelectron spectroscopy (XPS), it was found that the interaction of the resulting Pd/HOPG sample with nitrogen dioxide at room temperature and a pressure of 10–6 mbar led to the oxidation of graphite. In this case, palladium particles retained their metallic state. A comparison with the behavior of a palladium sample supported onto HOPG activated by ion etching under similar conditions showed that structural defects on the graphite surface did not play a decisive role in the oxidation of graphene layers. A comparison with the results obtained upon the interaction of NO2 with Pt nanoparticles supported on the HOPG surface was made. © 2020, Pleiades Publishing, Ltd.
Cite: Smirnov M.Y. , Kalinkin A.V. , Sorokin A.M. , Bukhtiyarov V.I.
Room Temperature Interaction of NO2 with Palladium Nanoparticles Supported on a Nonactivated Surface of Highly Oriented Pyrolytic Graphite (HOPG)
Kinetics and Catalysis. 2020. V.61. N6. P.907-911. DOI: 10.1134/S0023158420060142 WOS Scopus РИНЦ AN OpenAlex
Original: Смирнов М.Ю. , Калинкин А.В. , Сорокин А.М. , Бухтияров В.И.
Взаимодействие NO2 с наночастицами палладия, нанесенными на неактивированную поверхность высоко ориентированного пиролитического графита (ВОПГ), при комнатной температуре
Кинетика и катализ. 2020. Т.61. №6. С.893-898. DOI: 10.31857/s0453881120060155RSCI РИНЦ OpenAlex
Dates:
Submitted: Mar 15, 2020
Accepted: Apr 17, 2020
Published print: Nov 1, 2020
Published online: Dec 28, 2020
Identifiers:
Web of science: WOS:000603310400011
Scopus: 2-s2.0-85098288490
Elibrary: 45047883
Chemical Abstracts: 2021:20775
OpenAlex: W3115924458
Citing:
DB Citing
Scopus 7
Web of science 7
Elibrary 6
OpenAlex 7
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