Water Vapor Adsorption on CAU-10-X: Effect of Functional Groups on Adsorption Equilibrium and Mechanisms | Sciact - CRIS-система Института катализа

Water Vapor Adsorption on CAU-10-X: Effect of Functional Groups on Adsorption Equilibrium and Mechanisms Научная публикация

Журнал

Langmuir
ISSN: 0743-7463 , E-ISSN: 1520-5827

Вых. Данные

Год: 2021, Том: 37, Номер: 2, Страницы: 693–702 Страниц : 10 DOI: 10.1021/acs.langmuir.0c02729

Ключевые слова

METAL-ORGANIC FRAMEWORKS; DRIVEN HEAT-PUMPS; PROMISING MATERIAL; TRANSFORMATION; STABILITY; STORAGE; CONDUCTOR; INSULATOR; COATINGS; BEHAVIOR

Авторы

Solovyeva Marina V. ^1,2 , Shkatulov Alexandr I. ³ , Gordeeva Larisa G. ^1,2 , Fedorova Elizaveta A. ¹ , Krieger Tamara A. ¹ , Aristov Yuri I. ^1,2

Организации

1	Boreskov Institute of Catalysis, Novosibirsk, Ac. Lavrentiev av. 5, Novosibirsk 630090, Russia
2	Novosibirsk State University, Novosibirsk, Pirogova str. 2, Novosibirsk 630090, Russia
3	Eindhoven University of Technology, Department of Applied Physics, De Rondom 70, 5612 AP, Eindhoven, The Netherlands

Информация о финансировании (2)

1	Федеральное агентство научных организаций России	0303-2016-0013
2	Российский фонд фундаментальных исследований	18-29-04033

Metal–organic frameworks (MOFs) possess unique flexibility of structure and properties, which drives them toward applications as water adsorbents in many emerging technologies, such as adsorptive heat transformation, water harvesting from the air, dehumidification, and desalination. A deep understanding of the surface phenomena is a prerequisite for the target-oriented design of MOFs with the required adsorption properties. In this work, we comprehensively study the effect of functional groups on water adsorption on a series CAU-10-X substituted with both hydrophilic (X = NH2) and hydrophobic (X = NO2) groups in the linker. The adsorption equilibrium is measured at P = 7.6–42 mbar and T = 5–100 °C. The study of water adsorption by a set of mutually complementary physicochemical methods (TG, XRD in situ, FTIR, and 1H NMR relaxometry) elucidates the nature of primary adsorption sites and water adsorption mechanisms.

Solovyeva M.V. , Shkatulov A.I. , Gordeeva L.G. , Fedorova E.A. , Krieger T.A. , Aristov Y.I.
Water Vapor Adsorption on CAU-10-X: Effect of Functional Groups on Adsorption Equilibrium and Mechanisms

Langmuir. 2021. V.37. N2. P.693–702. DOI: 10.1021/acs.langmuir.0c02729 WOS Scopus РИНЦ CAPlusCA PMID OpenAlex

Полный текст от издателя

Поступила в редакцию:	17 сент. 2020 г.
Принята к публикации:	23 дек. 2020 г.
Опубликована online:	7 янв. 2021 г.
Опубликована в печати:	19 янв. 2021 г.

Web of science:	WOS:000612351800011
Scopus:	2-s2.0-85100190703
РИНЦ:	44969206
Chemical Abstracts:	2021:52471
Chemical Abstracts (print):	175:154447
PMID (PubMed):	33412006
OpenAlex:	W3118464915

БД	Цитирований
Scopus	28
Web of science	27
РИНЦ	25
OpenAlex	28