Water Vapor Adsorption on CAU-10-X: Effect of Functional Groups on Adsorption Equilibrium and Mechanisms Научная публикация
Журнал |
Langmuir
ISSN: 0743-7463 , E-ISSN: 1520-5827 |
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Вых. Данные | Год: 2021, Том: 37, Номер: 2, Страницы: 693–702 Страниц : 10 DOI: 10.1021/acs.langmuir.0c02729 | ||||||
Ключевые слова | METAL-ORGANIC FRAMEWORKS; DRIVEN HEAT-PUMPS; PROMISING MATERIAL; TRANSFORMATION; STABILITY; STORAGE; CONDUCTOR; INSULATOR; COATINGS; BEHAVIOR | ||||||
Авторы |
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Организации |
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Информация о финансировании (2)
1 | Федеральное агентство научных организаций России | 0303-2016-0013 |
2 | Российский фонд фундаментальных исследований | 18-29-04033 |
Реферат:
Metal–organic frameworks (MOFs) possess unique flexibility of structure and properties, which drives them toward applications as water adsorbents in many emerging technologies, such as adsorptive heat transformation, water harvesting from the air, dehumidification, and desalination. A deep understanding of the surface phenomena is a prerequisite for the target-oriented design of MOFs with the required adsorption properties. In this work, we comprehensively study the effect of functional groups on water adsorption on a series CAU-10-X substituted with both hydrophilic (X = NH2) and hydrophobic (X = NO2) groups in the linker. The adsorption equilibrium is measured at P = 7.6–42 mbar and T = 5–100 °C. The study of water adsorption by a set of mutually complementary physicochemical methods (TG, XRD in situ, FTIR, and 1H NMR relaxometry) elucidates the nature of primary adsorption sites and water adsorption mechanisms.
Библиографическая ссылка:
Solovyeva M.V.
, Shkatulov A.I.
, Gordeeva L.G.
, Fedorova E.A.
, Krieger T.A.
, Aristov Y.I.
Water Vapor Adsorption on CAU-10-X: Effect of Functional Groups on Adsorption Equilibrium and Mechanisms
Langmuir. 2021. V.37. N2. P.693–702. DOI: 10.1021/acs.langmuir.0c02729 WOS Scopus РИНЦ CAPlusCA PMID OpenAlex
Water Vapor Adsorption on CAU-10-X: Effect of Functional Groups on Adsorption Equilibrium and Mechanisms
Langmuir. 2021. V.37. N2. P.693–702. DOI: 10.1021/acs.langmuir.0c02729 WOS Scopus РИНЦ CAPlusCA PMID OpenAlex
Файлы:
Полный текст от издателя
Даты:
Поступила в редакцию: | 17 сент. 2020 г. |
Принята к публикации: | 23 дек. 2020 г. |
Опубликована online: | 7 янв. 2021 г. |
Опубликована в печати: | 19 янв. 2021 г. |
Идентификаторы БД:
Web of science: | WOS:000612351800011 |
Scopus: | 2-s2.0-85100190703 |
РИНЦ: | 44969206 |
Chemical Abstracts: | 2021:52471 |
Chemical Abstracts (print): | 175:154447 |
PMID (PubMed): | 33412006 |
OpenAlex: | W3118464915 |