OLED Thin Film Fabrication from Poorly Soluble Terbium o-Phenoxybenzoate through Soluble Mixed-Ligand Complexes | Sciact - CRIS-system of Boreskov Institute of Catalysis

OLED Thin Film Fabrication from Poorly Soluble Terbium o-Phenoxybenzoate through Soluble Mixed-Ligand Complexes Full article

Journal

Organic Electronics
ISSN: 1566-1199

Output data

Year: 2016, Volume: 28, Pages: 319-329 Pages count : 11 DOI: 10.1016/j.orgel.2015.11.006

Tags

Electroluminescence; Lanthanide carboxylates; OLED; Spin-coating; Ternary complexes; Thin film

Authors

Kalyakina Alena S. ^1,7 , Utochnikova Valentina V. ^1,2,3 , Sokolova Elena Yu. ¹ , Vashchenko Andrey A. ^2,8 , Lepnev Leonid S. ² , Van Deun Rik ⁴ , Trigub Alexander L. ⁵ , Zubavichus Yan V. ⁵ , Hoffmann Michael ⁶ , Mühl Susan ⁶ , Kuzmina Natalia P. ¹

Affiliations

1	Lomonosov Moscow State University
2	P.N. Lebedev Physical Institute, Russian Academy of Sciences
3	SIA Evoled, 1A Pushkina iela, Riga, Latvia
4	L3-Luminescent Lanthanide Lab, Ghent University, Krijgslaan 281, S3, 9000 Gent, Belgium
5	NRC«Kurchatov Institute»
6	Fraunhofer Institute for Organic Electronics, Electron Beam and Plasma Technology FEP, Maria-Reiche-Straße 2, 01109 Dresden, Germany
7	Institute of Organic Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 6, D-76131 Karlsruhe, Germany
8	Moscow Institute of Physics and Technology (State University)

Features and advantages of the approach of the luminescent thin film deposition of non-volatile and non-soluble lanthanide aromatic carboxylates were exemplified by thin film deposition of terbium o-phenoxybenzoate Tb(pobz)3(H2O)2 (I) with quantum yield measured to be 96%. This approach is based on the formation and decomposition of mixed-ligand complexes, and thus mixed-ligand complex Tb(pobz)3(MG)(H2O)2 (II) (MG – monoglyme) was synthesized, characterized and used as a precursor for I thin films. Electroluminescent (EL) properties of high quality thin films of I and those with suitable host material were studied in a series of OLED devices.

Kalyakina A.S. , Utochnikova V.V. , Sokolova E.Y. , Vashchenko A.A. , Lepnev L.S. , Van Deun R. , Trigub A.L. , Zubavichus Y.V. , Hoffmann M. , Mühl S. , Kuzmina N.P.
OLED Thin Film Fabrication from Poorly Soluble Terbium o-Phenoxybenzoate through Soluble Mixed-Ligand Complexes
Organic Electronics. 2016. V.28. P.319-329. DOI: 10.1016/j.orgel.2015.11.006 WOS Scopus РИНЦ AN OpenAlex

Submitted:	Aug 6, 2015
Accepted:	Nov 8, 2015
Published online:	Dec 10, 2015
Published print:	Jan 1, 2016

Web of science:	WOS:000367775300048
Scopus:	2-s2.0-85009454923
Elibrary:	29471356
Chemical Abstracts:	2015:1920281
OpenAlex:	W2156496406

DB	Citing
Web of science	31
Scopus	32
OpenAlex	32