Reactivity of Platinum Hydrides in the Selective Hydrogenation of Acetic Acid on Pt–ReOx/TiO2 Catalysts Full article
| Journal |
Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555 |
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| Output data | Year: 2020, Volume: 12, Number: 4, Pages: 316-322 Pages count : 7 DOI: 10.1134/s207005042004011x | ||||
| Tags | hydrogenation of carboxylic acids, platinum, rhenium, hydride, IR spectroscopy | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Foundation for Basic Research | 19-53-51002 |
| 2 | National Research Foundation of Korea | NRF-2019K2A9A1A06098926 |
Abstract:
The interaction between hydrogen and subnanometer deposited Pt–ReOx particles active in dehydrogenation of carboxylic acids is investigated via in situ diffuse reflectance IR spectroscopy. Absorption bands of platinum hydrides are detected in the range of 2025–2043 cm−1, and their high reactivity with respect to adsorbed acetic acid is revealed. The absorption band of platinum hydride shifts toward higher frequencies and becomes more intense, due to the effect of adjacent acetates on the electron state of platinum. It is established that in a hydrogen medium the intensity of platinum hydride bands sharply increases after the adsorption of acetic acid and then gradually decreases owing to the reaction of the hydrides with surface acetates.
Cite:
Makolkin N.V.
, Kim H.U.
, Paukshtis E.A.
, Jae J.
, Bal’zhinimaev B.S.
Reactivity of Platinum Hydrides in the Selective Hydrogenation of Acetic Acid on Pt–ReOx/TiO2 Catalysts
Catalysis in Industry. 2020. V.12. N4. P.316-322. DOI: 10.1134/s207005042004011x WOS Scopus РИНЦ OpenAlex
Reactivity of Platinum Hydrides in the Selective Hydrogenation of Acetic Acid on Pt–ReOx/TiO2 Catalysts
Catalysis in Industry. 2020. V.12. N4. P.316-322. DOI: 10.1134/s207005042004011x WOS Scopus РИНЦ OpenAlex
Original:
Маколкин Н.В.
, Kim H.U.
, Паукштис Е.А.
, Jae J.
, Бальжинимаев Б.С.
Реакционная способность гидридов платины в селективном гидрировании уксусной кислоты на Pt-ReOx /TiO2 катализаторах
Катализ в промышленности. 2020. Т.20. №6. С.426-432. DOI: 10.18412/1816-0387-2020-6-426-432 РИНЦ AN OpenAlex
Реакционная способность гидридов платины в селективном гидрировании уксусной кислоты на Pt-ReOx /TiO2 катализаторах
Катализ в промышленности. 2020. Т.20. №6. С.426-432. DOI: 10.18412/1816-0387-2020-6-426-432 РИНЦ AN OpenAlex
Dates:
| Submitted: | Sep 30, 2019 |
| Accepted: | Oct 21, 2020 |
| Published print: | Oct 21, 2020 |
| Published online: | Jan 27, 2021 |
Identifiers:
| Web of science: | WOS:000612367000006 |
| Scopus: | 2-s2.0-85099825669 |
| Elibrary: | 44987929 |
| OpenAlex: | W3126331383 |