Sciact
  • EN
  • RU

The Unique Structure of [(C4H9)4N]3[Pb(NO3)5] — One Step Forward in Understanding Transport Properties in tetra-n-butylammonium-based Solid Electrolytes Научная публикация

Журнал Structural Chemistry
ISSN: 1040-0400 , E-ISSN: 1572-9001
Вых. Данные Год: 2021, Том: 32, Страницы: 1261–1267 Страниц : 7 DOI: 10.1007/s11224-021-01732-y
Ключевые слова Crystal structure; High-temperature conductivity; Organic ionic plastic crystals; Tetra-n-butylammonium; Tris(tetrabutylammonium) pentanitratoplumbate(II)
Авторы Asanbaeva Nargiz B. 1,2,3 , Rychkov Denis A. 1,3 , Tyapkin Pavel Yu. 1 , Arkhipov Sergey G. 3,4 , Uvarov Nikolay F. 1,3,5
Организации
1 Institute of Solid State Chemistry and Mechanochemistry SB RAS, 18 Kutateladze st., Novosibirsk, Russia 630128
2 N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry SB RAS, 9 Ac. Lavrentiev Avenue, Novosibirsk, Russia 630090
3 Novosibirsk State University, 2 Pirogova str., Novosibirsk, Russia 630090
4 Boreskov Institute of Catalysis SB RAS, 5 Lavrentiev Ave., Novosibirsk, Russia 630090
5 Novosibirsk State Technical University, 20 K. Marksa Ave., Novosibirsk, Russia 630073

Информация о финансировании (2)

1 Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) ГЗ-2021-2023
2 Российский научный фонд 20-13-00302

Реферат: The crystal and molecular structure of tris(tetrabutylammonium) pentanitratoplumbate(II) was determined and characterized by single-crystal and powder X-ray diffraction and IR spectroscopy. The structure is compared to other tetra-n-butylammonium-based metal complexes with inorganic ligands, showing a significant difference in space group and local surroundings. The Pb2+ cation is surrounded by five NO3− groups, forming a stable complex only in the crystal field. Part of (C4H9)4N+ cations are distorted significantly changing geometry from tetrahedra to almost flat (square) at room temperature. Discussion on possible reorientational motion of organic groups at high temperatures and its influence on ion transport processes within the crystal structure of tetra-n-butylammonium-based organic ionic plastic crystals is provided. © 2021, The Author(s), under exclusive licence to Springer Science+Business Media, LLC part of Springer Nature.
Библиографическая ссылка: Asanbaeva N.B. , Rychkov D.A. , Tyapkin P.Y. , Arkhipov S.G. , Uvarov N.F.
The Unique Structure of [(C4H9)4N]3[Pb(NO3)5] — One Step Forward in Understanding Transport Properties in tetra-n-butylammonium-based Solid Electrolytes
Structural Chemistry. 2021. V.32. P.1261–1267. DOI: 10.1007/s11224-021-01732-y WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
Поступила в редакцию: 17 дек. 2020 г.
Принята к публикации: 14 янв. 2021 г.
Опубликована online: 28 янв. 2021 г.
Опубликована в печати: 1 июн. 2021 г.
Идентификаторы БД:
Web of science: WOS:000612570600001
Scopus: 2-s2.0-85099930143
РИНЦ: 44983774
Chemical Abstracts: 2021:235754
OpenAlex: W3123835436
Цитирование в БД:
БД Цитирований
Scopus 5
Web of science 5
РИНЦ 4
OpenAlex 6
Альметрики: