Features of Crystal and Local Structures of Complex Oxides Formed in the Binary System Dy2O3-ZrO2 Full article
| Conference |
Международная конференция «Плазменные, лазерные исследования и технологии» (ПЛИТ 2016) 25-27 Jan 2016 , Москва |
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| Journal |
Journal of Physics: Conference Series
ISSN: 1742-6588 , E-ISSN: 1742-6596 |
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| Output data | Year: 2016, Volume: 747, Article number : 012042, Pages count : 5 DOI: 10.1088/1742-6596/747/1/012042 | ||||
| Tags | NANOCRYSTALLINE STRUCTURES; PYROCHLORES; Dy; Ln; ZIRCONIA; Gd | ||||
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Abstract:
The process of Dy2Zr2O7 (rDy3+/rZr4+ = 1.426) nanocrystals formation and evolution upon calcinations up to 1400 oC has been investigated by means of synchrotron radiation X-ray diffraction (XRD) and Raman spectroscopy. We observed that isothermal calcination of the X-ray amorphous precursor first leads to the formation of oxide nanocrystalline powders with a defect fluorite structure at 800 oC/3 h. The nucleation and growth of pyrochlore phase take place in nanodomains with pyrochlore-type superstructural ordering of cations and anions inside a well crystalline fluorite matrix at > 1200 oC. This is perhaps the first XRD study that reports the presence of a weak pyrochlore-type superstructure in the Dy2Zr2O7.
Cite:
Popov V.V.
, Menushenkov A.P.
, Yastrebtsev A.A.
, Zubavichus Y.V.
, Svetogorov R.D.
, Kolyshkin N.A.
Features of Crystal and Local Structures of Complex Oxides Formed in the Binary System Dy2O3-ZrO2
Journal of Physics: Conference Series. 2016.
V.747. 012042
:1-5. DOI: 10.1088/1742-6596/747/1/012042
WOS
Scopus
РИНЦ
AN
OpenAlex
Features of Crystal and Local Structures of Complex Oxides Formed in the Binary System Dy2O3-ZrO2
Journal of Physics: Conference Series. 2016.
V.747. 012042
:1-5. DOI: 10.1088/1742-6596/747/1/012042
WOS
Scopus
РИНЦ
AN
OpenAlex
Files:
Full text from publisher
Dates:
| Submitted: | Sep 1, 2016 |
| Published print: | Sep 1, 2016 |
| Published online: | Sep 21, 2016 |
Identifiers:
| Web of science: | WOS:000387066400042 |
| Scopus: | 2-s2.0-84992145718 |
| Elibrary: | 27586892 |
| Chemical Abstracts: | 2016:1907627 |
| OpenAlex: | W2523086552 |