Synthesis, Structure, Photo- and Electroluminescent Properties of bis{(4-methyl-N-[2-[(E)-2-pyridyliminomethyl]phenyl)]benzenesulfonamide}zinc(II) | Sciact - CRIS-система Института катализа

Synthesis, Structure, Photo- and Electroluminescent Properties of bis{(4-methyl-N-[2-[(E)-2-pyridyliminomethyl]phenyl)]benzenesulfonamide}zinc(II) Научная публикация

Журнал

Polyhedron
ISSN: 0277-5387

Вых. Данные

Год: 2017, Том: 133, Страницы: 231-237 Страниц : 7 DOI: 10.1016/j.poly.2017.05.045

Ключевые слова

Azomethines; Luminescence; OLED; TD-DFT; Zinc complex

Авторы

Burlov Anatolii S. ¹ , Mal'tsev Eugenii I. ² , Vlasenko Valery G. ³ , Garnovskii Dmitrii A. ⁴ , Dmitriev Artem V. ² , Lypenko Dmitrii A. ² , Vannikov Anatoly V. ² , Dorovatovskii Pavel V. ⁵ , Lazarensko Vladimir A. ⁵ , Zubavichus Yan V. ⁵ , Khrustalev Victor N. ⁶

Организации

1	Institute of Physical and Organic Chemistry of Southern Federal University
2	A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of RAS
3	Institute of Physics of Southern Federal University
4	Southern Scientific Centre of Russian Academy of Sciences
5	NRC Kurchatov Institute
6	Department of Inorganic Chemistry, Peoples’ Friendship University of Russia (RUDN University)

The synthesis, structure and spectroscopic properties of luminescent Zn(II) complex containing 4-methyl-N-[2-[(E)-pyridinylmethyl]phenyl]benzosulfimide ligand are described. The Zn(II) complex was characterized by single-crystal X-ray diffraction study. Time-dependent density functional theory calculations at the B3LYP/6-31G∗ level were performed on Zn(II) complex to interpretation its experimental UV–Vis absorption spectrum. OLED device with Zn(II) complex as light-emitting layer has been fabricated. The electroluminescent spectrum of OLED showed a dominant yellow emission at 525 nm (Commission Internationale de l’eclairage (CIE) coordinates x = 0.409 and y = 0.506) and a weak shoulder at 650 nm without any other distinguishing emission from host or adjacent layers. The fabricated OLED generated luminance of more than 1000 cd/m2 at 16 V, current density 600 mA/cm2 and rather low turn-on voltage of ca. 4 V and power efficiency 1 lm/W.

Burlov A.S. , Mal'tsev E.I. , Vlasenko V.G. , Garnovskii D.A. , Dmitriev A.V. , Lypenko D.A. , Vannikov A.V. , Dorovatovskii P.V. , Lazarensko V.A. , Zubavichus Y.V. , Khrustalev V.N.
Synthesis, Structure, Photo- and Electroluminescent Properties of bis{(4-methyl-N-[2-[(E)-2-pyridyliminomethyl]phenyl)]benzenesulfonamide}zinc(II)
Polyhedron. 2017. V.133. P.231-237. DOI: 10.1016/j.poly.2017.05.045 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	17 апр. 2017 г.
Принята к публикации:	23 мая 2017 г.
Опубликована online:	1 июн. 2017 г.
Опубликована в печати:	5 сент. 2017 г.

Web of science:	WOS:000405537200030
Scopus:	2-s2.0-85020429907
РИНЦ:	31020101
Chemical Abstracts:	2017:965355
Chemical Abstracts (print):	167:136858
OpenAlex:	W2620885748

БД	Цитирований
Web of science	24
Scopus	25
OpenAlex	25