Hybrid Materials Based on Polymethylsilsesquioxanes Containing Fe, Pt, and Fe–Pt Metallic Nanoparticles | Sciact - CRIS-system of Boreskov Institute of Catalysis

Hybrid Materials Based on Polymethylsilsesquioxanes Containing Fe, Pt, and Fe–Pt Metallic Nanoparticles Full article

Journal

Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X

Output data

Year: 2017, Volume: 91, Number: 11, Pages: 2188-2194 Pages count : 7 DOI: 10.1134/s0036024417110310

Tags

metal vapor synthesis, metallic nanoparticles, hybride materials, polymethylsilsesquioxane, magnetic properties

Authors

Vasil’kov A.Yu. ¹ , Migulin D.A. ² , Naumkin A.V. ¹ , Zubavichus Ya.V. ³ , Budnikov A.V. ¹ , Ellert O.G. ⁴ , Maksimov Yu.V. ⁵ , Muzafarov A.M. ^1,2

Affiliations

1	Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
2	Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences
3	National Research Center Kurchatov Institute
4	Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
5	Semenov Institute of Chemical Physics, Russian Academy of Sciences

New hybrid materials based on Pt, Fe, and Pt–Fe nanoparticles stabilized in a matrix of polymethylsilsesquioxane nanogel and ultrahigh molecular weight polyethylene (UHMWPE) were prepared. Metal vapor synthesis was used to produce mono- and bimetallic nanoparticles. It was shown that organosilicon nanogel effectively stabilizes Pt nanoparticles with an average size of 0.9 nm. Using the nanogel results in the formation of superparamagnetic Fe particles 3–5 nm in size that consist of ferromagnetic Fe0 core and antiferromagnetic shells of Fe oxides. It is established that using an organosilicon matrix in the formation of Pt-Fe/UHMWPE systems helps reduce the average particle size of Fe in the material from 6.5 to 4.5 nm and narrow their particle size distribution. The composition, magnetic and electronic characteristics of the nanocomposites are studied via transmission electron microscopy, X-ray photoelectron spectroscopy, Mössbauer spectroscopy, XANES, and EXAFS.

Vasil’kov A.Y. , Migulin D.A. , Naumkin A.V. , Zubavichus Y.V. , Budnikov A.V. , Ellert O.G. , Maksimov Y.V. , Muzafarov A.M.
Hybrid Materials Based on Polymethylsilsesquioxanes Containing Fe, Pt, and Fe–Pt Metallic Nanoparticles
Russian Journal of Physical Chemistry A. 2017. V.91. N11. P.2188-2194. DOI: 10.1134/s0036024417110310 WOS Scopus РИНЦ ANCAN OpenAlex

Васильков А.Ю. , Мигулин Д.А. , Наумкин А.В. , Зубавичус Я.В. , Будников А.В. , Эллерт О.Г. , Максимов Ю.В. , Музафаров А.М.
Гибридные материалы на основе полиорганосилсесквиоксанов, содержащие наночастицы металлов Fe, Pt и Fe–Pt
Журнал физической химии. 2017. Т.91. №11. С.1898-1905. DOI: 10.7868/S0044453717110358 РИНЦ OpenAlex

Submitted:	Jan 12, 2017
Published online:	Oct 1, 2017
Published print:	Nov 1, 2017

Web of science:	WOS:000412092100020
Scopus:	2-s2.0-85030164798
Elibrary:	31051465
Chemical Abstracts:	2017:1583891
Chemical Abstracts (print):	168:503081
OpenAlex:	W2753250695

DB	Citing
Web of science	2
Scopus	3
OpenAlex	3