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Effect of Fe-Substitution on the Structure and Magnetism of Single Crystals Mn2-xFexBO4 Full article

Journal Journal of Crystal Growth
ISSN: 0022-0248
Output data Year: 2017, Volume: 475, Pages: 239-246 Pages count : 8 DOI: 10.1016/j.jcrysgro.2017.06.026
Tags A1. Crystal structure; A1. Low dimensional structures; A2. Single crystal growth; B1. Borates; B2. Magnetic materials
Authors Platunov M.S. 1,2 , Kazak N.V. 1 , Knyazev Yu.V. 1 , Bezmaternykh L.N. 1 , Moshkina E.M. 1 , Trigub A.L. 3 , Veligzhanin A.A. 3 , Zubavichus Y.V. 3 , Solovyov L.A. 4 , Velikanov D.A. 1 , Ovchinnikov S.G. 1
Affiliations
1 Kirensky Institute of Physics, Federal Research Center KSC SB RAS
2 ESRF-The European Synchrotron
3 National Research Centre ‘‘Kurchatov Institute”
4 Institute of Chemistry and Chemical Technology, Federal Research Center KSC SB RAS

Abstract: Single crystalline Mn2-xFexBO4 with x = 0.3, 0.5, 0.7 grown by the flux method have been studied by means of X-ray diffraction and X-ray absorption spectroscopy at both Mn and Fe K edges. The compounds were found to crystallize in an orthorhombic warwickite structure (sp. gr. Pnam). The lattice parameters change linearly with x thus obeying the Vegard’s law. The Fe3+ substitution for Mn3+ has been deduced from the X-ray absorption near-edge structure (XANES) spectra. Two energy positions of the absorption edges have been observed in Mn K-edge XANES spectra indicating the presence of manganese in two different oxidation states. Extended X-ray absorption fine structure (EXAFS) analysis has shown the reduction of local structural distortions upon Fe substitution. The magnetization data have revealed a spin-glass transition at TSG = 11, 14 and 18 K for x = 0.3, 0.5 and 0.7, respectively.
Cite: Platunov M.S. , Kazak N.V. , Knyazev Y.V. , Bezmaternykh L.N. , Moshkina E.M. , Trigub A.L. , Veligzhanin A.A. , Zubavichus Y.V. , Solovyov L.A. , Velikanov D.A. , Ovchinnikov S.G.
Effect of Fe-Substitution on the Structure and Magnetism of Single Crystals Mn2-xFexBO4
Journal of Crystal Growth. 2017. V.475. P.239-246. DOI: 10.1016/j.jcrysgro.2017.06.026 WOS Scopus РИНЦ ANCAN OpenAlex
Files: Full text from publisher
Dates:
Submitted: Apr 12, 2017
Accepted: Jun 29, 2017
Published online: Jun 30, 2017
Published print: Oct 1, 2017
Identifiers:
Web of science: WOS:000410916300033
Scopus: 2-s2.0-85021980854
Elibrary: 31068659
Chemical Abstracts: 2017:1143807
Chemical Abstracts (print): 167:514940
OpenAlex: W2712447460
Citing:
DB Citing
Web of science 8
Scopus 8
OpenAlex 9
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