Ferrocene-Containing Tri- and Tetranuclear Cyclic Copper(i) and Silver(i) Pyrazolates Full article
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Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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| Output data | Year: 2017, Volume: 66, Number: 9, Pages: 1563-1568 Pages count : 6 DOI: 10.1007/s11172-017-1925-2 | ||||||
| Tags | copper(i); ferrocenylpyrazole; Group 11 metal pyrazolates; silver(i) | ||||||
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Abstract:
New tri- and tetranuclear macrocyclic silver(I) and copper(I) 3-ferrocenyl-5-(trifluoromethyl)pyrazolates were prepared: [{(3-((η5-C5H4)Fe(η5-C5H5))-5-(CF3)-Pz}M]3 (M = Cu (1), Ag (2)) and [{(3-(( η5-C5H4)Fe(η5-C5H5))-5-(CF3)-Pz}Cu]4 (3). The structures of compounds were established by X-ray diffraction analysis. In the crystalline state, a planar trinuclear silver-containing macrocycliс pyrazolate and a saddle-shaped tetranuclear copper-containing macrocycle are formed. The introduction of a bulky substituent, ferrocene, into the pyrazole ligand results in complete shielding of the acidic metal sites, which precludes the coordination of base molecules.
Cite:
Titov A.A.
, Smol´yakov A.F.
, Rodionov A.N.
, Kosenko I.D.
, Guseva E.A.
, Zubavichus Y.V.
, Dorovatovskii P.V.
, Filippov O.A.
, Shubina E.S.
Ferrocene-Containing Tri- and Tetranuclear Cyclic Copper(i) and Silver(i) Pyrazolates
Russian Chemical Bulletin. 2017. V.66. N9. P.1563-1568. DOI: 10.1007/s11172-017-1925-2 WOS Scopus РИНЦ ANCAN OpenAlex
Ferrocene-Containing Tri- and Tetranuclear Cyclic Copper(i) and Silver(i) Pyrazolates
Russian Chemical Bulletin. 2017. V.66. N9. P.1563-1568. DOI: 10.1007/s11172-017-1925-2 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Титов А.А.
, Смольяков А.Ф.
, Родионов А.Н.
, Косенко И.Д.
, Гусева Е.А.
, Зубавичус Я.В.
, Дороватовский П.В.
, Филиппов О.А.
, Шубина Е.С.
Ферроценсодержащие трех- и четырехъядерные циклические пиразолаты меди(I) и серебра(I)
Известия Академии наук. Серия химическая. 2017. №9. С.1563-1568. РИНЦ
Ферроценсодержащие трех- и четырехъядерные циклические пиразолаты меди(I) и серебра(I)
Известия Академии наук. Серия химическая. 2017. №9. С.1563-1568. РИНЦ
Dates:
| Submitted: | Jun 26, 2017 |
| Accepted: | Jul 3, 2017 |
| Published print: | Sep 1, 2017 |
| Published online: | Dec 28, 2017 |
Identifiers:
| Web of science: | WOS:000418825200006 |
| Scopus: | 2-s2.0-85039435719 |
| Elibrary: | 35512734 |
| Chemical Abstracts: | 2018:16611 |
| Chemical Abstracts (print): | 168:144405 |
| OpenAlex: | W2776060911 |