Electrochemical Synthesis and Structure of 2-amino-1-ethylbenzimidazole Adducts of Copper, Cobalt, and Zinc Chelates in the N,N,S Ligand Environment | Sciact - CRIS-system of Boreskov Institute of Catalysis

Electrochemical Synthesis and Structure of 2-amino-1-ethylbenzimidazole Adducts of Copper, Cobalt, and Zinc Chelates in the N,N,S Ligand Environment Full article

Journal

Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 , E-ISSN: 1531-8613

Output data

Year: 2017, Volume: 62, Number: 8, Pages: 1077-1084 Pages count : 8 DOI: 10.1134/s0036023617080071

Tags

aminoheterocycles; electrochemical synthesis; magnetochemistry; metal-containing pharmaceuticals; Schiff bases; X-ray spectral and X-ray diffraction analysis

Authors

Garnovskii D.A. ¹ , Aleksandrov G.G. ² , Makarova N.I. ³ , Levchenkov S.I. ¹ , Vlasenko V.G. ⁴ , Zubavichus Ya.V. ⁵ , Uraev A.I. ³ , Burlov A.S. ³

Affiliations

1	Southern Scientific Center, Russian Academy of Sciences
2	Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
3	Institute of Physical and Organic Chemistry, Southern Federal University
4	Research Institute of Physics, Southern Federal University
5	National Research Center “Kurchatov Institute”

2-Amino-1-ethylbenzimidazole (L1) adducts with copper(II), cobalt(II), and zinc(II) chelates of N,N,S tridentate tosylamino-functionalized mercaptopyrazole-containing Schiff base (H2L), resulting from condensation of 2-tosylaminoaniline with 1-phenyl-3-methyl-4-formylpyrazole-5-thiol, with the general formula [ML · L1] were obtained by electrochemical method. The structure and composition of the complexes were confirmed by the data of C, H, N elemental analysis, IR and 1H NMR spectroscopy, and magnetochemical and X-ray spectral measurements. The mononuclear structure of the copper(II) adduct with coordination bond located on the pyridine type endocyclic nitrogen atom of 2-amino-1-ethylbenzimidazole was proved by X-ray diffraction.

Garnovskii D.A. , Aleksandrov G.G. , Makarova N.I. , Levchenkov S.I. , Vlasenko V.G. , Zubavichus Y.V. , Uraev A.I. , Burlov A.S.
Electrochemical Synthesis and Structure of 2-amino-1-ethylbenzimidazole Adducts of Copper, Cobalt, and Zinc Chelates in the N,N,S Ligand Environment
Russian Journal of Inorganic Chemistry. 2017. V.62. N8. P.1077-1084. DOI: 10.1134/s0036023617080071 WOS Scopus РИНЦ AN OpenAlex

Гарновский Д.А. , Александров Г.Г. , Макарова Н.И. , Левченков С.И. , Власенко В.Г. , Зубавичус Я.В. , Ураев А.И. , Бурлов А.С.
Электрохимический синтез и строение аддуктов 2-амино-1-этилбензимидазола хелатов меди, кобальта и цинка в N, N, S лигандном окружении
Журнал неорганической химии. 2017. Т.62. №8. С.1078-1086. DOI: 10.7868/S0044457X17080098 РИНЦ OpenAlex

Submitted:	Jun 15, 2016
Published print:	Aug 1, 2017
Published online:	Aug 30, 2017

Web of science:	WOS:000408698500010
Scopus:	2-s2.0-85028553465
Elibrary:	31066605
Chemical Abstracts:	2017:1403145
OpenAlex:	W2751531999

DB	Citing
Web of science	4
Scopus	5
OpenAlex	5